Research Progress of Intramolecular π‐Stacked Small Molecules for Device Applications
Organic semiconductors can be designed and constructed in π‐stacked structures instead of
the conventional π‐conjugated structures. Through‐space interaction (TSI) occurs in π …
the conventional π‐conjugated structures. Through‐space interaction (TSI) occurs in π …
Recent developments in and perspectives on three-coordinate boron materials: a bright future
L Ji, S Griesbeck, TB Marder - Chemical Science, 2017 - pubs.rsc.org
The empty pz-orbital of a three-coordinate organoboron compound leads to its electron-
deficient properties, which make it an excellent π-acceptor in conjugated organic …
deficient properties, which make it an excellent π-acceptor in conjugated organic …
A Facile Molecular Machine: Optically Triggered Counterion Migration by Charge Transfer of Linear Donor‐π‐Acceptor Phosphonium Fluorophores
The D‐π‐A type phosphonium salts in which electron acceptor (A=‐+ PR3) and donor (D=‐
NPh2) groups are linked by polarizable π‐conjugated spacers show intense fluorescence …
NPh2) groups are linked by polarizable π‐conjugated spacers show intense fluorescence …
Tunable luminescence of bithiophene-based flexible Lewis pairs
Bithiophene-based flexible Lewis pairs with P (O) R2 (R= phenyl, isopropyl) and BMes2
(Mes= 2, 4, 6-trimethylphenyl) functionalities are able to toggle between closed, Lewis …
(Mes= 2, 4, 6-trimethylphenyl) functionalities are able to toggle between closed, Lewis …
Dual-emissive difluoroboron naphthyl-phenyl β-diketonate polylactide materials: effects of heavy atom placement and polymer molecular weight
J Samonina-Kosicka, CA DeRosa, WA Morris… - …, 2014 - ACS Publications
Luminescent materials are important for imaging and sensing. Aromatic difluoroboron β-
diketonate complexes (BF2bdks) are classic fluorescent molecules that have been explored …
diketonate complexes (BF2bdks) are classic fluorescent molecules that have been explored …
Multiple Emission of Phosphonium Fluorophores Harnessed by the Pathways of Photoinduced Counterion Migration
In the emerging field of intramolecular charge transfer induced counterion migration, we
report the new insights into photophysical features of luminescent donor–acceptor …
report the new insights into photophysical features of luminescent donor–acceptor …
Cationic organophosphorus chromophores: A diamond in the rough among ionic dyes
Tunable electron‐accepting properties of the cationic phosphorus center, its geometry and
unique preparative chemistry that allows combining this unit with diversity of π‐conjugated …
unique preparative chemistry that allows combining this unit with diversity of π‐conjugated …
Near-unity thermally activated delayed fluorescence efficiency in three-and four-coordinate Au (I) complexes with diphosphine ligands
M Osawa, M Aino, T Nagakura, M Hoshino… - Dalton …, 2018 - pubs.rsc.org
The synthesis and photoluminescence properties of three-coordinate Au (I) complexes with
rigid diphosphine ligands LMe {1, 2-bis [bis (2-methylphenyl) phosphino] benzene}, LEt {1, 2 …
rigid diphosphine ligands LMe {1, 2-bis [bis (2-methylphenyl) phosphino] benzene}, LEt {1, 2 …
The influence of linkers on quantum interference: A linker theorem
How heteroatomic substitutions affect electron transport through π-conjugated hydrocarbons
has been the subject of some debate. In this paper we investigate the effect of heteroatomic …
has been the subject of some debate. In this paper we investigate the effect of heteroatomic …
Competition between intra and intermolecular triel bonds. Complexes between naphthalene derivatives and neutral or anionic Lewis bases
A TrF2 group (Tr= B, Al, Ga, In, Tl) is placed on one of the α positions of naphthalene, and its
ability to engage in a triel bond (TrB) with a weak (NCH) and strong (NC−) nucleophile is …
ability to engage in a triel bond (TrB) with a weak (NCH) and strong (NC−) nucleophile is …