Organic photoredox catalysis

NA Romero, DA Nicewicz - Chemical reviews, 2016 - ACS Publications
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic
transformations with a range of applications. This overview is arranged by catalyst class …

Recent advancements in applications of ionic liquids in synthetic construction of heterocyclic scaffolds: A spotlight

TM Dhameliya, PR Nagar, KA Bhakhar… - Journal of Molecular …, 2022 - Elsevier
Heterocycles constitute the integral part of the most of United States food and drug
administration (USFDA) approved drugs. Over the past decade, ionic liquids have emerged …

[HTML][HTML] Photochemical oxidation of benzylic primary and secondary alcohols utilizing air as the oxidant

NF Nikitas, DI Tzaras, I Triandafillidi, CG Kokotos - Green Chemistry, 2020 - pubs.rsc.org
A mild and green photochemical protocol for the oxidation of alcohols to aldehydes and
ketones was developed. Utilizing thioxanthenone as the photocatalyst, molecular oxygen …

Metal-free catalyst for visible-light-induced oxidation of unactivated alcohols using air/oxygen as an oxidant

W Schilling, D Riemer, Y Zhang, N Hatami, S Das - ACS Catalysis, 2018 - ACS Publications
9-Fluorenone acts as a metal-free and additive-free photocatalyst for the selective oxidation
of primary and secondary alcohols under visible light. With this photocatalyst, a plethora of …

Synthesis and Excited-State Properties of Donor–Acceptor Azahelical Coumarins

K Jana, D Sarkar, P Jaiswal… - The Journal of Organic …, 2023 - ACS Publications
A set of three donor–acceptor azahelical coumarins (DA-AHC s), namely, H-AHC, Me-AHC,
and Ph-AHC, were rationally designed and synthesized, and their excited-state properties …

Ultrafast intersystem crossing in xanthone from wavepacket dynamics

M Alías-Rodríguez, C de Graaf… - Journal of the American …, 2021 - ACS Publications
Most aromatic ketones containing first-row elements undergo unexpectedly fast intersystem
crossing in a few tens of picoseconds and a quantum yield close to unity. Among them …

Solvent effects on the optical spectra and excited-state decay of triphenylamine-thiadiazole with hybridized local excitation and intramolecular charge transfer

D Fan, Y Yi, Z Li, W Liu, Q Peng… - The Journal of Physical …, 2015 - ACS Publications
The triphenylamine-thiadiazole molecule (TPA-NZP) is a newly popular, highly efficient
OLED fluorescent emitter with exciton utilization efficiency exceeding the upper limit of spin …

Regulating local polarization in truxenone-based covalent organic frameworks for boosting photocatalytic hydrogen evolution

L Hao, R Shen, C Qin, N Li, H Hu, G Liang, X Li - Science China Materials, 2024 - Springer
The high local charge delocalization and strong dipole moment are two key factors that
affect the photocatalytic hydrogen evolution over covalent organic frameworks (COFs) …

Perspectives for uranyl photoredox catalysis

D Hu, X Jiang - Synlett, 2021 - thieme-connect.com
The application of uranyl salts as powerful photoredox catalysts in chemical transformations
lags behind the advances achieved in thermocatalysis and structural chemistry. In fact …

Synthesis, properties, and application of phenanthrenone: an undeveloped building block and a photocatalyst

Z Gan, J Zhou, L Zhu, X Chen, Q Ma, J Yan… - Organic Chemistry …, 2023 - pubs.rsc.org
The synthesis, properties, and application of carbonyl-bridged phenanthrene, namely
phenanthrenone, are described. A novel synthetic route involving palladium-catalyzed …