Microhydration prevents fragmentation of uracil and thymine by low-energy electrons

J Kocisek, A Pysanenko, M Fárník… - The Journal of Physical …, 2016 - ACS Publications
When ionizing radiation passes biological matter, a large number of secondary electrons
with very low energies (< 3 eV) is produced. It is known that such electrons cause an efficient …

Radiation‐Induced Transfer of Charge, Atoms, and Energy within Isolated Biomolecular Systems

F Chevalier, T Schlathölter, JC Poully - ChemBioChem, 2023 - Wiley Online Library
In biological tissues, ionizing radiation interacts with a variety of molecules and the
consequences include cell killing and the modification of mechanical properties …

Comparing pulsed and continuous laser-induced acoustic desorption (LIAD) as sources for intact biomolecules

S Wang, GL Abma, P Krüger, A van Roij… - The European Physical …, 2022 - Springer
A major obstacle to the gas-phase study of larger (bio) molecular systems is the vaporisation
step, that is, the introduction of intact sample molecules into the gas-phase. A promising …

Water is a radiation protection agent for ionised pyrrole

M Johny, CA Schouder, A Al-Refaie, L He… - Physical Chemistry …, 2024 - pubs.rsc.org
Radiation-induced damage of biological matter is an ubiquitous problem in nature. The
influence of the hydration environment is widely discussed, but its exact role remains …

Spectroscopic Characterization of Hydrogen-Bonded 2, 7-Diazaindole Water Complex Isolated in the Gas Phase

S Baweja, B Kalal, S Maity - The Journal of Physical Chemistry A, 2024 - ACS Publications
We present a systematic experimental analysis of the 1: 1 complex of 2, 7-diazaindole
(27DAI) with water in the gas phase. The complex was characterized by using two-color …

Study of electron ionization and fragmentation of non-hydrated and hydrated tetrahydrofuran clusters

M Neustetter, M Mahmoodi-Darian… - Journal of The American …, 2017 - ACS Publications
Mass spectroscopic investigations on tetrahydrofuran (THF, C4H8O), a common model
molecule of the DNA-backbone, have been carried out. We irradiated isolated THF and …

Thermal desorption effects on fragment ion production from multi-photon ionized uridine and selected analogues

J Bocková, A Rebelo, M Ryszka, R Pandey… - RSC …, 2021 - pubs.rsc.org
Experiments on neutral gas-phase nucleosides are often complicated by thermal lability.
Previous mass spectrometry studies of nucleosides have identified enhanced relative …

Dissociative multi-photon ionization of isolated uracil and uracil-adenine complexes

M Ryszka, R Pandey, C Rizk, J Tabet, B Barc… - International Journal of …, 2016 - Elsevier
Recent multi-photon ionization (MPI) experiments on uracil revealed a fragment ion at m/z
84 that was proposed as a potential marker for ring opening in the electronically excited …

Stabilities of nanohydrated thymine radical cations: insights from multiphoton ionization experiments and ab initio calculations

R Pandey, M Lalande, M Ryszka… - The European Physical …, 2017 - Springer
Multi-photon ionization experiments have been carried out on thymine-water clusters in the
gas phase. Metastable H 2 O loss from T+(H 2 O) n was observed at n≥ 3 only. Ab initio …

Proton migration in clusters consisting of protonated pyridine solvated by water molecules

F Berthias, L Feketeová, H Chermette… - …, 2015 - Wiley Online Library
Proton transfer (PT) from protonated pyridine to water molecules is observed after excitation
of microhydrated protonated pyridine (Py) clusters PyH+ (H2O) n (n= 0–5) is induced by a …