Electron transfer reactions are among the most elementary of all chemical reactions and
play a fundamental role in many areas including organic synthesis, biological processes …

Reactions that involve transfer of an electron and a proton can proceed by stepwise
pathways involving initial electron transfer (ET) or initial proton transfer (PT), or by a …

Understanding the energy it takes to build or break chemical bonds is essential for scientists
and engineers in a wide range of innovative fields, including catalysis, nanomaterials …

The second edition of this best-selling handbook is bigger, more comprehensive, and now
completely current. In addition to thorough updates to the discussions featured in the first …

A thorough understanding of reaction thermochem-istry is essential in orderto distinguish
between mechanistic possibilities. In the gas phase, thermo-dynamic relationships between …

A CuI catalyst (1), supported by a framework of strongly basic guanidinato moieties,
mediates nitrene-transfer from PhI NR sources to a wide variety of aliphatic hydrocarbons …

The enthalpy change that occurs in a photoinduced chemical reaction in solution can be
quantified by a relatively simple technique known as photoacoustic calorimetry (PAC), which …

The concept of antiaromaticity in cyclic conjugated organic molecules was introduced by
Breslow, 1 who proposed there are magnetic, spectroscopic, and thermodynamic criteria for …

A coordinatively saturated ruthenium (II) complex having tetradentate tris (2-pyridylmethyl)
amine (TPA) and bidentate 2, 2′-bipyridine (bpy),[Ru (TPA)(bpy)] 2+(1), was oxidized by a …

The electrochemical oxidation and reduction potentials of substituted benzyl, cumyl, and
diphenylmethyl radicals are found to give linear correlationswith+ and", respectively (p+ …