C (sp3) atoms as tetrel bond donors: A crystallographic survey
The σ-hole and π-hole interactions allow for a systematic understanding of some features of
the attractive interactions involving elements of groups 13–18 of the periodic table and of …
the attractive interactions involving elements of groups 13–18 of the periodic table and of …
Recent advances in the chemistry of scandium
SA Cotton - Polyhedron, 1999 - Elsevier
3 3 3 concerned solely with its co-ordination chemistry. The impression that a co-ordination
number of six was the 1994 review of Schaverien covered scandium within its norm …
number of six was the 1994 review of Schaverien covered scandium within its norm …
Structural chemistry of Sc (III): an overview
PR Meehan, DR Aris, GR Willey - Coordination chemistry reviews, 1999 - Elsevier
Structural aspects of the chemistry of organometallic/coordination compounds of scandium
(III) are reviewed. Individual compounds are classified and discussed in terms of …
(III) are reviewed. Individual compounds are classified and discussed in terms of …
Syntheses of cis- and trans-Dibenzo-30-Crown-10 Derivatives via Regioselective Routes and Their Complexations with Paraquat and Diquat
C He, Z Shi, Q Zhou, S Li, N Li… - The Journal of organic …, 2008 - ACS Publications
cis-Dibenzo-30-crown-10 (cis-DB30C10) diester and trans-dibenzo-30-crown-10 (trans-
DB30C10) diester were synthesized regioselectively with reasonable yields. These two …
DB30C10) diester were synthesized regioselectively with reasonable yields. These two …
Inclusion of a Cu2+ Ion by a Large-Cavity Crown Ether Dibenzo-24-Crown-8 through Supramolecular Interactions
V Shivaiah, SK Das - Inorganic chemistry, 2005 - ACS Publications
A supramolecular copper− aqua− crown ether complex,[CuII (H2O) 4 (dibenzo-24-crown-8]
2+(1c) is stabilized with a Lindqvist-type polyoxometalate anion,[MoVI6O19] 2-(1a), in an ion …
2+(1c) is stabilized with a Lindqvist-type polyoxometalate anion,[MoVI6O19] 2-(1a), in an ion …
Primary and secondary coordination of crown ethers to scandium (iii). Synthesis, properties and structures of the reaction products of ScCl 3 (thf) 3, ScCl 3· 6H 2 O and …
MD Brown, W Levason, DC Murray, MC Popham… - Dalton …, 2003 - pubs.rsc.org
The synthesis and spectroscopic characterisation of [ScCl (15-crown-5)(MeCN)][SbCl6]
2,[ScCl2 (18-crown-6)][FeCl4] and [ScCl2 ([15] aneS2O3)][FeCl4]([15] aneS2O3= 1, 4-dithia …
2,[ScCl2 (18-crown-6)][FeCl4] and [ScCl2 ([15] aneS2O3)][FeCl4]([15] aneS2O3= 1, 4-dithia …
Scandium halide complexes of phosphine-and arsine-oxides: synthesis, structures and 45Sc NMR studies
NJ Hill, W Levason, MC Popham, G Reid, M Webster - Polyhedron, 2002 - Elsevier
The reactions of ScCl3· 6H2O, ScBr3· 6H2O and ScI3· 8H2O with Ph3PO, Ph3AsO,
Ph2MePO, Me3PO and Me3AsO have been examined in EtOH or Me2CO solution. The new …
Ph2MePO, Me3PO and Me3AsO have been examined in EtOH or Me2CO solution. The new …
Halide abstraction reactions of tin(IV) chloride and the group 3 chlorides MCl3 (M = Sc, Y, La) in thf: crystal and molecular structure of [ScCl2(thf)4][SnCl5(thf)]
GR Willey, TJ Woodman, W Errington - Transition Metal Chemistry, 1998 - Springer
Abstract Direct treatment (1: 1) of MCl 3 (M= Sc, Y or La) with SnCl4 in thf provides
colourless compounds of the type ScSnCl 7 (thf) 5 and MSnCl 7 (thf) 6 (M= Y, La), which …
colourless compounds of the type ScSnCl 7 (thf) 5 and MSnCl 7 (thf) 6 (M= Y, La), which …
Solution state chemistry of scandium (III): a study of scandium-crown ether complexes by 45Sc-NMR spectroscopy
PR Meehan, GR Willey - Inorganica chimica acta, 1999 - Elsevier
Addition of SbCl5 (1mol) to ScCl3 (THF) 3 (1mol) in acetonitrile followed by in situ addition of
a crown ether (1mol) provides the [ScCl2 (crown)][SbCl6] complexes where crown= 15 …
a crown ether (1mol) provides the [ScCl2 (crown)][SbCl6] complexes where crown= 15 …