First-generation organic reaction intermediates in zeolite chemistry and catalysis

X Gong, M Caglayan, Y Ye, K Liu, J Gascon… - Chemical …, 2022 - ACS Publications
Zeolite chemistry and catalysis are expected to play a decisive role in the next decade (s) to
build a more decentralized renewable feedstock-dependent sustainable society owing to the …

A tale of two methane monooxygenases

MO Ross, AC Rosenzweig - JBIC Journal of Biological Inorganic …, 2017 - Springer
Methane monooxygenase (MMO) enzymes activate O 2 for oxidation of methane. Two
distinct MMOs exist in nature, a soluble form that uses a diiron active site (sMMO) and a …

C H Bond Activation in Transition Metal Species from a Computational Perspective

D Balcells, E Clot, O Eisenstein - Chemical reviews, 2010 - ACS Publications
Alkanes constitute the cheapest and most abundant feedstock for organic chemicals.
However, the redistribution of CsC and CsH bonds in hydrocarbons into more sophisticated …

Direct Methane Oxidation by Copper-and Iron-Dependent Methane Monooxygenases

FJ Tucci, AC Rosenzweig - Chemical reviews, 2024 - ACS Publications
Methane is a potent greenhouse gas that contributes significantly to climate change and is
primarily regulated in Nature by methanotrophic bacteria, which consume methane gas as …

Viewpoint on the partial oxidation of methane to methanol using Cu-and Fe-exchanged zeolites

KT Dinh, MM Sullivan, P Serna, RJ Meyer… - Acs …, 2018 - ACS Publications
Abundant and inexpensive reserves of CH4, obtained from increased production of natural
gas, can effortlessly be incorporated into the current petrochemical infrastructure via the …

Dioxygen activation and methane hydroxylation by soluble methane monooxygenase: a tale of two irons and three proteins

M Merkx, DA Kopp, MH Sazinsky… - Angewandte Chemie …, 2001 - Wiley Online Library
Methanotrophic bacteria are capable of using methane as their sole source of carbon and
energy. The first step in methane metabolism, the oxidation of methane to methanol, is …

Soluble methane monooxygenase

R Banerjee, JC Jones… - Annual review of …, 2019 - annualreviews.org
Aerobic life is possible because the molecular structure of oxygen (O2) makes direct
reaction with most organic materials at ambient temperatures an exceptionally slow process …

Mechanistic studies on the hydroxylation of methane by methane monooxygenase

MH Baik, M Newcomb, RA Friesner… - Chemical …, 2003 - ACS Publications
Methanotrophs are bacteria that live on methane as their only source of carbon. 1 The first
step in their utilization of this simplest of all hydrocarbons is its selective conversion to …

Role of the secondary coordination sphere in metal-mediated dioxygen activation

RL Shook, AS Borovik - Inorganic chemistry, 2010 - ACS Publications
Alfred Werner proposed nearly 100 years ago that the secondary coordination sphere has a
role in determining the physical properties of transition-metal complexes. We now know that …

Selective alkane transformations via radicals and radical cations: Insights into the activation step from experiment and theory

AA Fokin, PR Schreiner - Chemical reviews, 2002 - ACS Publications
As the main constituent of natural gas, alkanes are arguably Nature's most plentiful organic
base chemicals that are easily accessible. Chemists have long coveted the use of alkanes …