Delocalisation of photoexcited triplet states probed by transient EPR and hyperfine spectroscopy

S Richert, CE Tait, CR Timmel - Journal of Magnetic Resonance, 2017 - Elsevier
Photoexcited triplet states play a crucial role in photochemical mechanisms: long known to
be of paramount importance in the study of photosynthetic reaction centres, they have more …

Recent advances on anthracene-based photoinitiators of polymerization

F Dumur - European Polymer Journal, 2022 - Elsevier
Photopolymerization is an active research field, and this intense research activity is
supported by the numerous and emerging applications related to this polymerization …

Reversible spin-optical interface in luminescent organic radicals

S Gorgon, K Lv, J Grüne, BH Drummond, WK Myers… - Nature, 2023 - nature.com
Molecules present a versatile platform for quantum information science, and are candidates
for sensing and computation applications,. Robust spin-optical interfaces are key to …

Near-infrared luminescent open-shell π-conjugated systems with a bright lowest-energy zwitterionic singlet excited state

CP Yu, R Chowdhury, Y Fu, P Ghosh, W Zeng… - Science …, 2024 - science.org
Open-shell systems with extensive π-conjugation have fascinating properties due to their
narrow bandgaps and spin interactions. In this work, we report neutral open-shell di-and …

Singlet‐Triplet Energy Inversion in Carbon Nitride Photocatalysts

A Actis, M Melchionna, G Filippini… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Time‐resolved EPR (TR‐EPR) demonstrates the formation of well‐defined spin
triplet excitons in carbon nitride. This permits to experimentally probe the extent of the triplet …

Computational tools for the simulation and analysis of spin-polarized EPR spectra

CE Tait, MD Krzyaniak, S Stoll - Journal of Magnetic Resonance, 2023 - Elsevier
The EPR spectra of paramagnetic species induced by photoexcitation typically exhibit
enhanced absorptive and emissive features resulting from sublevel populations that differ …

Charge and Spin Transfer Dynamics in a Weakly Coupled Porphyrin Dimer

SM Kopp, AJ Redman, I Roncevic… - Journal of the …, 2024 - ACS Publications
The dynamics of electron and spin transfer in the radical cation and photogenerated triplet
states of a tetramethylbiphenyl-linked zinc-porphyrin dimer were investigated, so as to test …

Does Twisted π-Conjugation Framework Always Induce Efficient Intersystem Crossing? A Case Study with Benzo[b]- and [a]Phenanthrene-Fused BODIPY …

Y Yan, AA Sukhanov, MHE Bousquet… - The Journal of …, 2021 - ACS Publications
The photophysical properties, especially the intersystem crossing (ISC) of two heavy-atom-
free BODIPY derivatives with twisted π-conjugated frameworks (benzo [b]-fused BODIPY …

Triplet fullerenes as prospective spin labels for nanoscale distance measurements by pulsed dipolar EPR spectroscopy

OA Krumkacheva, IO Timofeev… - Angewandte Chemie …, 2019 - Wiley Online Library
Precise nanoscale distance measurements by pulsed electron paramagnetic resonance
(EPR) spectroscopy play a crucial role in structural studies of biomolecules. The properties …

Structure–function relationship of organic semiconductors: detailed insights from time-resolved EPR spectroscopy

T Biskup - Frontiers in Chemistry, 2019 - frontiersin.org
Organic photovoltaics (OPV) is a promising technology to account for the increasing demand
for energy in form of electricity. Whereas the last decades have seen tremendous progress …