Catalytic carbene insertion into C− H bonds

MP Doyle, R Duffy, M Ratnikov, L Zhou - Chemical reviews, 2010 - ACS Publications
From its earliest observation as an unusual reaction only a half century ago, 1 the insertion
of a carbene into a carbonrhydrogen bond has attracted considerable interest because of its …

Recent Advances in the Construction of Phosphorus‐Substituted Heterocycles, 2009–2019

L Chen, XY Liu, YX Zou - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
Phosphorus‐substituted heterocycles represent an important class of organophosphorus
compounds, which not only widely exist in biologically active pharmaceuticals …

Recent advances in asymmetric reactions catalyzed by proline and its derivatives

J Liu, L Wang - Synthesis, 2017 - thieme-connect.com
Asymmetric reactions are carried out by organocatalysis in many ways, making them very
competitive and practical. One remarkable molecule, the amino acid proline, has become a …

Green-light-sensitive BODIPY photoprotecting groups for amines

K Sitkowska, BL Feringa… - The Journal of Organic …, 2018 - ACS Publications
We describe a series of easily accessible, visible-light-sensitive (λ> 500 nm) BODIPY (boron-
dipyrromethene)-based photoprotecting groups (PPGs) for primary and secondary amines …

Functionalized benzazines as luminescent materials and components for optoelectronics

EV Nosova, S Achelle, GN Lipunova… - Russian Chemical …, 2019 - iopscience.iop.org
Extensive research on the synthesis and application of benzazine derivatives for electronic
devices, luminescent elements, photoelectric conversion elements, and image sensors has …

Gold-catalyzed diastereoselective domino dearomatization/ipso-cyclization/aza-Michael sequence: a facile access to diverse fused azaspiro tetracyclic scaffolds

Y He, Z Li, G Tian, L Song, L Van Meervelt… - Chemical …, 2017 - pubs.rsc.org
A facile and diversity-oriented access to complex tetracyclic benzo [e] pyrrolo [2, 3-c] indole-
2, 4, 7 (5H)-triones through a post-Ugi gold (I)-catalyzed domino dearomatization/ipso …

Organocatalytically Generated Donor–Acceptor Cyclopropanes in Domino Reactions. One-Step Enantioselective Synthesis of Pyrrolo[1,2-a]quinolines

E Sanchez-Diez, DL Vesga, E Reyes, U Uria… - Organic …, 2016 - ACS Publications
An easy and straightforward procedure has been developed for the synthesis of highly
enantioenriched pyrrolo [1, 2-a] quinolines through a one-pot process that comprises a …

Diazoacetonitrile (N2CHCN): A Long Forgotten but Valuable Reagent for Organic Synthesis

PK Mykhailiuk, RM Koenigs - Chemistry–A European Journal, 2020 - Wiley Online Library
Diazoacetonitrile (N2CHCN) is a small reactive diazoalkane. It has been synthesized for the
first time already in 1898 by Theodor Curtius, however, did not gain much recognition in …

Palladium-catalyzed alkoxycarbonylation of arylsulfoniums

H Minami, K Nogi, H Yorimitsu - Organic letters, 2019 - ACS Publications
Alkoxycarbonylation of arylsulfoniums has been developed with the aid of a catalytic amount
of a palladium-Xantphos complex under an atmospheric pressure of CO gas. Various …

Chemoselective conversion from α-hydroxy acids to α-keto acids enabled by nitroxyl-radical-catalyzed aerobic oxidation

K Furukawa, H Inada, M Shibuya, Y Yamamoto - Organic letters, 2016 - ACS Publications
The chemoselective oxidation of α-hydroxy acids to α-keto acids catalyzed by 2-
azaadamantane N-oxyl (AZADO), a nitroxyl radical catalyst, is described. Although α-keto …