During last decades, significant advances have been made in iron-based spin crossover
(SCO) complexes, with a particular emphasis on achieving reversible and reproducible …

The synthesis and characterization of a new Co (II) spin‐crossover (SCO) complex based on
4′‐(4‐carboxyphenyl)− 2, 2′: 6′, 2 ″‐terpyridine ligand are reported. This complex can …

Little is known about the mechanisms behind the bistability (memory) of molecular spin
transition compounds over broad temperature ranges (> 100 K). To address this point, we …

The impact of solvent on spin crossover (SCO) behaviour is reported in two solvates [Fe
(qsal-I) 2] NO3· 2ROH (qsal-I= 4-iodo-2-[(8-quinolylimino) methyl] phenolate; R= Me 1 or Et …

Co-crystallization of the prominent Fe (II) spin-crossover (SCO) cation,[Fe (3-bpp) 2] 2+(3-
bpp= 2, 6-bis (pyrazol-3-yl) pyridine), with a fractionally charged TCNQδ− radical anion has …

The FeII coordination polymer,[Fe (NH2trz) 3](psca) 2· 2H2O (CP-1), incorporating a photo-
responsive non-coordinated anion, p-sulfocinnamic acid (psca), was synthesized in the …

Photoresponsive spin-crossover (SCO) molecules are an important class of bistable
magnetic molecules with intriguing potential in device applications. The light-induced …

Three mononuclear manganese (III) complexes based on flexible hexadentate ligands
obtained from the condensation of N, N′-bis (3-aminopropyl) ethylenediamine and …

Some transition metals have valence electrons that can form either high-or low-spin
complexes depending on their ligand field. The interconversion between high-to-low or low …

A bifunctionalized polyoxometalate (POM),[V6O19 (C16H15N6O) 2] 2−, which contains a
redox active hexavanadate moiety covalently linked to two tridentate 2, 6-bis (pyrazol-1-yl) …