Halogen radical oxidants in natural and engineered aquatic systems

K Zhang, KM Parker - Environmental science & technology, 2018 - ACS Publications
Photochemical reactions contribute to the transformation of contaminants and
biogeochemically important substrates in environmental aquatic systems. Recent research …

Centers of organic carbon burial and oxidation at the land-ocean interface

TS Bianchi, X Cui, NE Blair, DJ Burdige, TI Eglinton… - Organic …, 2018 - Elsevier
Continental margin systems collectively receive and store vast amounts of organic carbon
(OC) derived from primary productivity both on land and in the ocean, thereby playing a …

Rate Constants and Mechanisms of the Reactions of Cl and Cl2•– with Trace Organic Contaminants

Y Lei, S Cheng, N Luo, X Yang… - Environmental science & …, 2019 - ACS Publications
Cl• and Cl2•–radicals contribute to the degradation of trace organic contaminants (TrOCs)
such as pharmaceutical and personal care products and endocrine-disrupting chemicals …

Halogen radicals contribute to photooxidation in coastal and estuarine waters

KM Parker, WA Mitch - … of the National Academy of Sciences, 2016 - National Acad Sciences
Although halogen radicals are recognized to form as products of hydroxyl radical (• OH)
scavenging by halides, their contribution to the phototransformation of marine organic …

Bromine Radical (Br and Br2•–) Reactivity with Dissolved Organic Matter and Brominated Organic Byproduct Formation

Y Lei, X Lei, P Westerhoff, X Tong, J Ren… - Environmental …, 2022 - ACS Publications
Dissolved organic matter (DOM) is a major scavenger of bromine radicals (eg, Br• and Br2•–
) in sunlit surface waters and during oxidative processes used in water treatment. However …

Novel Chloroflexi genomes from the deepest ocean reveal metabolic strategies for the adaptation to deep-sea habitats

R Liu, X Wei, W Song, L Wang, J Cao, J Wu, T Thomas… - Microbiome, 2022 - Springer
Background The deep sea harbors the majority of the microbial biomass in the ocean and is
a key site for organic matter (OM) remineralization and storage in the biosphere. Microbial …

Offshore marine sediment microbiota respire structurally distinct organohalide pollutants

G Xu, N Zhang, X Zhao, C Chen… - … Science & Technology, 2022 - ACS Publications
Marine sediments are a major sink of organohalide pollutants, but the potential for offshore
marine microbiota to transform these pollutants remains underexplored. Here, we report …

Organohalide respiration in pristine environments: implications for the natural halogen cycle

S Atashgahi, MM Häggblom… - Environmental …, 2018 - Wiley Online Library
Halogenated organic compounds, also termed organohalogens, were initially considered to
be of almost exclusively anthropogenic origin. However, over 5000 naturally synthesized …

Aromatic Structures Govern the Formation of Chlorinated Byproducts in Dichlorine Radical Reactions

J Guan, X Lei, M Fan, Y Lei, J Qiu… - Environmental Science & …, 2024 - ACS Publications
Radical-induced disinfection byproduct (DBP) formation is drawing attention with increasing
applications of advanced oxidation processes (AOPs). Cl2•–represents one of the …

Roles of Organohalide-Respiring Dehalococcoidia in Carbon Cycling

Y Yang, R Sanford, J Yan, G Chen, NL Cápiro, X Li… - Msystems, 2020 - Am Soc Microbiol
The class Dehalococcoidia within the Chloroflexi phylum comprises the obligate
organohalide-respiring genera Dehalococcoides, Dehalogenimonas, and “Candidatus …