Sublimable spin‐crossover complexes: From spin‐state switching to molecular devices

KS Kumar, M Ruben - Angewandte Chemie International …, 2021 - Wiley Online Library
Spin‐crossover (SCO) active transition metal complexes are an important class of
switchable molecular materials due to their bistable spin‐state switching characteristics at or …

Metallopolymers for advanced sustainable applications

Y Wang, D Astruc, AS Abd-El-Aziz - Chemical Society Reviews, 2019 - pubs.rsc.org
Since the development of metallopolymers, there has been tremendous interest in the
applications of this type of materials. The interest in these materials stems from their …

Driving barocaloric effects in a molecular spin-crossover complex at low pressures

J Seo, JD Braun, VM Dev, JA Mason - Journal of the American …, 2022 - ACS Publications
Barocaloric effects─ thermal changes in a material induced by applied hydrostatic
pressure─ offer promise for creating solid-state refrigerants as alternatives to conventional …

Synthesis of contra-helical trefoil knots with mechanically tuneable spin-crossover properties

L Wu, M Tang, L Jiang, Y Chen, L Bian, J Liu… - Nature …, 2023 - nature.com
Molecular knots attract attention on account of their topological intricacies and potential
application. Tying molecular knots with different topologies, on larger length scales, remains …

Unprecedented switching endurance affords for high-resolution surface temperature mapping using a spin-crossover film

K Ridier, AC Bas, Y Zhang, L Routaboul… - Nature …, 2020 - nature.com
Temperature measurement at the nanoscale is of paramount importance in the fields of
nanoscience and nanotechnology, and calls for the development of versatile, high …

[HTML][HTML] Pressure effect investigations on spin-crossover coordination compounds

AB Gaspar, G Molnár, A Rotaru, HJ Shepherd - Comptes Rendus Chimie, 2018 - Elsevier
The piezochromic properties of spin-crossover complexes have been recognized for a long
time, with increasing pressure favouring the low spin state due to its smaller volume and …

[HTML][HTML] Thermodynamical aspects of the spin crossover phenomenon

W Nicolazzi, A Bousseksou - Comptes Rendus Chimie, 2018 - Elsevier
Fundamental aspects of spin crossover (SCO) mechanisms are reviewed through
considerations of ligand/crystal field theory, thermodynamics, and modeling of the …

Molecular spin crossover materials: Review of the lattice dynamical properties

G Molnár, M Mikolasek, K Ridier, A Fahs… - Annalen der …, 2019 - Wiley Online Library
The lattice dynamical aspects of the spin crossover phenomenon in molecular solids—
displaying intricate couplings between the electronic spin state of the molecules and the …

Colossal expansion and fast motion in spin-crossover@ polymer actuators

M Piedrahita-Bello, JE Angulo-Cervera… - Materials …, 2021 - pubs.rsc.org
Bilayer spin crossover (SCO)@ polymer nanocomposites show robust and controllable
actuation cycles upon an electrical stimulus. The anisotropic shape of the embedded …

Energy Conversion in Single‐Crystal‐to‐Single‐Crystal Phase Transition Materials

Y Zheng, X Jia, K Li, J Xu, XH Bu - Advanced Energy Materials, 2022 - Wiley Online Library
Abstract Single‐crystal‐to‐single‐crystal (SCSC) phase transitions are direct structural
evolutions of crystalline materials in the solid state without the damage of ordering in the …