Inhibition of the decomposition pathways of ruthenium olefin metathesis catalysts: Development of highly efficient catalysts for ethenolysis

R Gawin, A Tracz, P Krajczy… - Journal of the …, 2023 - ACS Publications
Ruthenium-based Hoveyda-type olefin metathesis catalysts bearing novel rigid spirocyclic
alkyl amino carbenes (CAACs) have been developed. They are characterized by …

Syntheses and Applications of Indol-2-ylidene-Ligated Ruthenium-Based Olefin Metathesis Catalysts

M Kim, H Kim, S Kim, S Hong, E Lee - Organometallics, 2022 - ACS Publications
Ru-based catalysts bearing ambiphilic carbenes exhibit exceptionally high turnover
numbers (TONs) in olefin metathesis reactions. However, the syntheses of these catalysts …

Synthesis and Application of Robust Spiro [Fluorene‑9] CAAC Ruthenium Alkylidene Complexes for the „One‐Pot “Conversion of Allyl Acetate to Butane‐1, 4‐diol

Á Erdélyi, V Farkas, G Turczel… - … A European Journal, 2024 - Wiley Online Library
A series of a novel CAAC ligands featuring a spiro‐fluorene group have been synthesized
and complexed with ruthenium alkylidenes, yielding the corresponding Hoveyda‐type …

油酸甲酯与乙烯复分解反应的研究进展.

程键, 李世文, 马占芳, 李化毅 - Biomass Chemical …, 2024 - search.ebscohost.com
油酸甲酯与乙烯复分解反应是一类特殊的烯烃复分解反应, 经过交叉复分解反应获得1-癸烯和9-
癸烯酸甲酯两种端烯中间体, 同时存在竞争性反应生成9-十八烯和9-十八烯-1, 18-二甲酯 …

Syntheses and activities of indol-2-ylidene-ligated ruthenium-based olefin metathesis catalysts

M Kim, H Kim, S Kim, S Hong, E Lee - 2022 - chemrxiv.org
Here we report a new family of indol-2-ylidene (IdY)-ligated Ru-based olefin metathesis
catalysts (Ru− IdY) and their X-ray crystal structures which show a unique conformation of …

Bulky, electron-rich, renewable: analogues of Beller's phosphine for cross-couplings

D Van der Westhuizen, AC Castro, N Hazari… - Catalysis Science & …, 2023 - pubs.rsc.org
In recent years, considerable progress has been made in the conversion of biomass into
renewable chemicals, yet the range of value-added products that can be formed from …