Nuclear magnetic resonance (NMR) is widely employed for investigating a range of
important issues from the determination of novel molecular structures in inorganic, organic …

Developments in the confinement of phosphines within micro-or nano-environments are
explored. Phosphines are ubiquitous across metal coordination chemistry and underpin …

Metal centers associated with cavities have attracted much attention, mainly because of their
resemblance to metalloenzymes.[1] Among concave molecules with a cavity, cyclodextrins …

Although quite common in nature, notably in metalloenzymes, the coordination of transition
metals within a confined three dimensional environment has long been hampered by the …

A β‐cyclodextrin‐based diphosphane with metal‐confining properties was efficiently
synthesized thanks to an unprecedented Smiles‐like rearrangement of diphenyl‐(2 …

Two confining phosphane ligands derived from either α‐or β‐cyclodextrin produce singly PIII‐
ligated metal complexes with unusual coordination spheres. High‐pressure NMR studies …

Cyclodextrin poly‐functionalization has fueled progress in their use in multiple applications
such as enzyme mimicry, but also in the polymer sciences, luminescence, as sensors or for …

This review is the fifth update of the original review, published in 1999, on the application of
MALDI mass spectrometry to the analysis of carbohydrates and glycoconjugates and brings …

Tertiary phosphines and other P (III)‐derivatives are the par excellence ligands in
industrially relevant homogeneous catalysis. A promising, recent development in this field …

The introduction of asymmetry in cyclic concave molecules constituted of achiral repeating
units can be achieved in various ways and leads to different types of chirality. This goal was …