Ultrasmall metal nanoparticles confined within crystalline nanoporous materials: a fascinating class of nanocatalysts
Crystalline nanoporous materials with uniform porous structures, such as zeolites and metal–
organic frameworks (MOFs), have proven to be ideal supports to encapsulate ultrasmall …
organic frameworks (MOFs), have proven to be ideal supports to encapsulate ultrasmall …
Confinement effects in zeolite‐confined noble metals
Confinement of noble nanometals in a zeolite matrix is a promising way to special types of
catalysts that show significant advantages in size control, site adjustment, and nano …
catalysts that show significant advantages in size control, site adjustment, and nano …
A Pd@ zeolite catalyst for nitroarene hydrogenation with high product selectivity by sterically controlled adsorption in the zeolite micropores
J Zhang, L Wang, Y Shao, Y Wang… - Angewandte …, 2017 - Wiley Online Library
The adsorption of molecules on metal nanoparticles can be sterically controlled through the
use of zeolite crystals, which enhances the product selectivity in hydrogenations of reactants …
use of zeolite crystals, which enhances the product selectivity in hydrogenations of reactants …
Tuning the structure of platinum particles on ceria in situ for enhancing the catalytic performance of exhaust gas catalysts
A dynamic structural behavior of Pt nanoparticles on the ceria surface under
reducing/oxidizing conditions was found at moderate temperatures (< 500° C) and exploited …
reducing/oxidizing conditions was found at moderate temperatures (< 500° C) and exploited …
Encapsulating palladium nanoparticles inside mesoporous MFI zeolite nanocrystals for shape‐selective catalysis
TL Cui, WY Ke, WB Zhang, HH Wang, XH Li… - Angewandte …, 2016 - Wiley Online Library
Pd nanoparticles were successfully encapsulated inside mesoporous silicalite‐1
nanocrystals (Pd@ mnc‐S1) by a one‐pot method. The as‐synthesized Pd@ mnc‐S1 with …
nanocrystals (Pd@ mnc‐S1) by a one‐pot method. The as‐synthesized Pd@ mnc‐S1 with …
Colloidal nanocrystals for heterogeneous catalysis
Catalytic materials are an essential component of the chemical industry. They find
applications in everything from fine chemical manufacturing to greenhouse gas mitigation …
applications in everything from fine chemical manufacturing to greenhouse gas mitigation …
Oxidation of bioethanol using zeolite‐encapsulated gold nanoparticles
With the ongoing developments in biomass conversion, the oxidation of bioethanol to
acetaldehyde may become a favorable and green alternative to the preparation from …
acetaldehyde may become a favorable and green alternative to the preparation from …
Rational construction of metal nanoparticles fixed in zeolite crystals as highly efficient heterogeneous catalysts
L Wang, S Xu, S He, FS Xiao - Nano Today, 2018 - Elsevier
The zeolites, a class of materials with uniform porosity, high crystallinity, structural diversity,
and large surface area, have been extensively studied in both synthesis and applications in …
and large surface area, have been extensively studied in both synthesis and applications in …
Concerted bimetallic nanocluster synthesis and encapsulation via induced zeolite framework demetallation for shape and substrate selective heterogeneous catalysis
T Iida, D Zanchet, K Ohara, T Wakihara… - Angewandte Chemie …, 2018 - Wiley Online Library
Bimetallic nanoparticle encapsulation in microporous zeolite crystals is a promising route for
producing catalysts with unprecedented reaction selectivities. Herein, a novel synthetic …
producing catalysts with unprecedented reaction selectivities. Herein, a novel synthetic …
A robust hollow metal–organic framework with enhanced diffusion for size selective catalysis
Single crystalline (SC) hollow metal–organic frameworks (MOFs) are excellent host
materials for molecular and nanoparticle catalysts. However, due to synthetic challenges …
materials for molecular and nanoparticle catalysts. However, due to synthetic challenges …