Ionic liquids as tool to improve enzymatic organic synthesis

T Itoh - Chemical Reviews, 2017 - ACS Publications
Ionic liquids (ILs) have now been acknowledged as reaction media for biotransformations.
The first three examples were reported in this field in 2000, and since then, numerous …

[HTML][HTML] Ionic liquids for development of heterogeneous catalysts based on nanomaterials for biocatalysis

A Wolny, A Chrobok - Nanomaterials, 2021 - mdpi.com
The development of effective methods of enzyme stabilization is key for the evolution of
biocatalytic processes. An interesting approach combines the stabilization process of …

[HTML][HTML] Applications of ionic liquids in whole-cell and isolated enzyme biocatalysis

HT Imam, V Krasňan, M Rebroš, AC Marr - Molecules, 2021 - mdpi.com
Ionic liquids have unique chemical properties that have fascinated scientists in many fields.
The effects of adding ionic liquids to biocatalysts are many and varied. The uses of ionic …

Silicon Oxycarbide (SiOC)-Supported Ionic Liquids: Heterogeneous Catalysts for Cyclic Carbonate Formation

P Mikšovsky, K Rauchenwald, S Naghdi… - ACS Sustainable …, 2024 - ACS Publications
Silicon oxycarbides (SiOCs) impregnated with tetrabutylammonium halides (TBAX) were
investigated as an alternative to silica-based supported ionic liquid phases for the …

Functionalization of porous cellulose with glyoxyl groups as a carrier for enzyme immobilization and stabilization

S Martins de Oliveira, S Velasco-Lozano… - …, 2021 - ACS Publications
The functionalization of the internal surface of macroporous carriers with glyoxyl groups has
proven to highly stabilize a large variety of enzymes through multipoint covalent …

Recent developments in biocatalysis in multiphasic ionic liquid reaction systems

LE Meyer, J von Langermann, U Kragl - Biophysical reviews, 2018 - Springer
Ionic liquids are well known and frequently used 'designer solvents' for biocatalytic
reactions. This review highlights recent achievements in the field of multiphasic ionic liquid …

Molybdenum and Tungsten Imido Alkylidene N‐Heterocyclic Carbene Catalysts Bearing Cationic Ligands for Use in Biphasic Olefin Metathesis

I Elser, R Schowner, W Frey… - Chemistry–A European …, 2017 - Wiley Online Library
Ionic Mo‐and W‐imido alkylidene N‐heterocyclic carbene (NHC) olefin metathesis
catalysts,[Mo {N‐2, 6‐(Me2) C6H3}(CHCMe2Ph)(IMesH2)(OTf)(PPS)] OTf (3),[Mo (N‐2, 6 …

Highly productive and enantioselective enzyme catalysis under continuous supported liquid–liquid conditions using a hybrid monolithic bioreactor

B Sandig, MR Buchmeiser - ChemSusChem, 2016 - Wiley Online Library
Enzyme‐containing ionic liquids (ILs) were immobilized in cellulose‐2.5‐acetate
microbeads particles embedded in a porous monolithic polyurethane matrix. This bioreactor …

[HTML][HTML] Chemo-enzymatic Baeyer–Villiger oxidation facilitated with lipases immobilized in the supported ionic liquid phase

A Szelwicka, A Wolny, M Grymel, S Jurczyk, S Boncel… - Materials, 2021 - mdpi.com
A novel method for chemo-enzymatic Baeyer–Villiger oxidation of cyclic ketones in the
presence of supported ionic liquid-like phase biocatalyst was designed. In this work, multi …

Supported ionic liquid phase (SILP) facilitated gas-phase enzyme catalysis–CALB catalyzed transesterification of vinyl propionate

C Lee, B Sandig, MR Buchmeiser… - Catalysis Science & …, 2018 - pubs.rsc.org
The supported ionic liquid phase (SILP) technology has been used to immobilize Candida
Antarctica Lipase B (CALB) within a hybrid monolith. The monolith was synthesized in situ …