Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

In recent years, research dealing with organic paramagnetic compounds such as stable
radicals and high-spin systems has been focused on applied aspects. Several key trends …

Two novel copper (II) complexes with tert-butyl 2-pyridyl nitroxide (2pyNO•),[Cu2+
(2pyNO−)(2pyNO•)] 2 (BF4−) 2 (1· BF4) and [Cu2+ (2pyNO−)(2pyNO•)] 2 (ClO4−) 2 (1 …

The largest antiferromagnetic coupling parameter was characterized to be 2 J/k B=− 15.9 (2)
K in [Gd (hfac) 3 (6bpyNO)], where 6bpyNO stands for 2, 2′-bipyridin-6-yl tert-butyl …

Antiferro-and ferromagnetic couplings were observed in [Gd (hfac) 3 (2pyNO)(H 2 O)] and
[Gd (hfac) 3 (HNN) 2], respectively, where 2pyNO stands for tert-butyl 2-pyridyl nitroxide and …

Three novel gadolinium (III)–radical complexes [GdIII (hfac) 3 (H2O)(L)][Gd-L; L= tert-butyl
phenyl nitroxide (phNO) and its derivatives (tert-butyl 3-tolyl nitroxide and tert-butyl 4-tert …

Expanded porphyrins are synthetic analogues of porphyrins consisting of at least 17 atoms
in a cyclic conjugated framework that contains at least three pyrrole or pyrrole-like …

Verdazyl-based complexes,[Zn (hfac) 2](m-Py-V) 2· CH 3 CN and [Cu (hfac) 2][m-Py-V-(pF)
2] 2, were successfully synthesized. For [Zn (hfac) 2](m-Py-V) 2· CH 3 CN, molecular orbital …

Abstract Although 1, 2, 4, 5‐tetrazines or s‐tetrazines have been known in the literature for
more than a century, their coordination chemistry has become increasingly popular in recent …

The ground spin-state of [Cu (phpyNO) 2 (H2O) 2](BF4) 2 was switched between S total= 1/2
and 3/2 across 175 K. On warming, the space group was changed from P 212121 to C 2221 …