Cooperativity in noncovalent interactions

AS Mahadevi, GN Sastry - Chemical reviews, 2016 - ACS Publications
After conquering the atomic structure about a century ago, chemists have been largely
interested in understanding the concept of chemical bond and the formation of a molecule …

Coordination cages based on bis (pyrazolylpyridine) ligands: structures, dynamic behavior, guest binding, and catalysis

MD Ward, CA Hunter, NH Williams - Accounts of Chemical …, 2018 - ACS Publications
Conspectus We describe here a family of coordination cages with interesting structural,
guest-binding, and catalytic properties. Flexible bridging ligands containing two bidentate …

Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes

CT McTernan, JA Davies, JR Nitschke - Chemical Reviews, 2022 - ACS Publications
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

Anion encapsulation and dynamics in self-assembled coordination cages

R Custelcean - Chemical Society Reviews, 2014 - pubs.rsc.org
The ability of cationic coordination cages to act as anion receptors is reviewed, with an
emphasis on the anion encapsulation chemistry and the dynamics of cage assembly, anion …

Anion-induced reconstitution of a self-assembling system to express a chloride-binding Co10L15 pentagonal prism

IA Riddell, MMJ Smulders, JK Clegg, YR Hristova… - Nature …, 2012 - nature.com
Biochemical systems are adaptable, capable of reconstitution at all levels to achieve the
functions associated with life. Synthetic chemical systems are more limited in their ability to …

Urea-Functionalized M4L6 Cage Receptors: Anion-Templated Self-Assembly and Selective Guest Exchange in Aqueous Solutions

R Custelcean, PV Bonnesen, NC Duncan… - Journal of the …, 2012 - ACS Publications
We present an extensive study of a novel class of de novo designed tetrahedral M4L6 (M=
Ni, Zn) cage receptors, wherein internal decoration of the cage cavities with urea anion …

An S10-Symmetric 5-Fold Interlocked [2]Catenane

TK Ronson, Y Wang, K Baldridge… - Journal of the …, 2020 - ACS Publications
The reaction of sym-pentakis (4-aminothiophenyl) corannulene with 2-formyl-6-
methylpyridine and CuI or 2-formyl-1, 10-phenanthroline and MII (M= Co, Zn) yields an S 10 …

Narcissistic, integrative, and kinetic self-sorting within a system of coordination cages

FJ Rizzuto, JR Nitschke - Journal of the American Chemical …, 2020 - ACS Publications
Many useful principles of self-assembly have been elucidated through studies of systems
where multiple components combine to create a single structure. More complex systems …

Selective Formation of S4- and T-Symmetric Supramolecular Tetrahedral Cages and Helicates in Polar Media Assembled via Cooperative Action of Coordination …

Q Shi, X Zhou, W Yuan, X Su, A Neniškis… - Journal of the …, 2020 - ACS Publications
We report on the synthesis and self-assembly study of novel supramolecular monomers
encompassing quadruple hydrogen-bonding motifs and metal-coordinating 2, 2′-bipyridine …

Shape-, size-, and functional group-selective binding of small organic guests in a paramagnetic coordination cage

S Turega, M Whitehead, BR Hall, AJHM Meijer… - Inorganic …, 2013 - ACS Publications
The host–guest chemistry of the octanuclear cubic coordination cage [Co8L12] 16+(where L
is a bridging ligand containing two chelating pyrazolyl-pyridine units connected to a central …