Oxide cathodes: functions, instabilities, self healing, and degradation mitigations

Y Dong, J Li - Chemical Reviews, 2022 - ACS Publications
Recent progress in high-energy-density oxide cathodes for lithium-ion batteries has pushed
the limits of lithium usage and accessible redox couples. It often invokes hybrid anion-and …

Structural Understanding for High‐Voltage Stabilization of Lithium Cobalt Oxide

C Lin, J Li, ZW Yin, W Huang, Q Zhao… - Advanced …, 2024 - Wiley Online Library
The rapid development of modern consumer electronics is placing higher demands on the
lithium cobalt oxide (LiCoO2; LCO) cathode that powers them. Increasing operating voltage …

An Overview on the Advances of LiCoO2 Cathodes for Lithium‐Ion Batteries

Y Lyu, X Wu, K Wang, Z Feng, T Cheng… - Advanced Energy …, 2021 - Wiley Online Library
LiCoO2, discovered as a lithium‐ion intercalation material in 1980 by Prof. John B.
Goodenough, is still the dominant cathode for lithium‐ion batteries (LIBs) in the portable …

Structural origin of the high-voltage instability of lithium cobalt oxide

J Li, C Lin, M Weng, Y Qiu, P Chen, K Yang… - Nature …, 2021 - nature.com
Layered lithium cobalt oxide (LiCoO2, LCO) is the most successful commercial cathode
material in lithium-ion batteries. However, its notable structural instability at potentials higher …

Cobalt-free, high-nickel layered oxide cathodes for lithium-ion batteries: Progress, challenges, and perspectives

Y Kim, WM Seong, A Manthiram - Energy Storage Materials, 2021 - Elsevier
High-nickel layered oxides are enabling extraordinary growth of electric vehicles market due
to its high energy density. Nonetheless, leading battery manufacturers are trying to cut down …

Dextran Sulfate Lithium as Versatile Binder to Stabilize High‐Voltage LiCoO2 to 4.6 V

H Huang, Z Li, S Gu, J Bian, Y Li, J Chen… - Advanced Energy …, 2021 - Wiley Online Library
High‐voltage LiCoO2 is an attractive cathode for ultra‐high energy lithium‐ion batteries in
the 5G era. However, the practical application of LiCoO2 is largely hindered by the unstable …

Lithium manganese spinel cathodes for lithium‐ion batteries

Y Huang, Y Dong, S Li, J Lee, C Wang… - Advanced Energy …, 2021 - Wiley Online Library
Spinel LiMn2O4, whose electrochemical activity was first reported by Prof. John B.
Goodenough's group at Oxford in 1983, is an important cathode material for lithium‐ion …

Advancing to 4.6 V Review and Prospect in Developing High‐Energy‐Density LiCoO2 Cathode for Lithium‐Ion Batteries

SD Zhang, MY Qi, SJ Guo, YG Sun, XX Tan… - Small …, 2022 - Wiley Online Library
Layered LiCoO2 (LCO) is one of the most important cathodes for portable electronic
products at present and in the foreseeable future. It becomes a continuous push to increase …

Conductive Li+ Moieties‐Rich Cathode Electrolyte Interphase with Electrolyte Additive for 4.6 V Well‐Cycled Li||LiCoO2 Batteries

K Guo, C Zhu, H Wang, S Qi, J Huang… - Advanced Energy …, 2023 - Wiley Online Library
Increasing the cut‐off voltage of cathodes can improve the energy density of Li|| LiCoO2
batteries. However, the electrolyte and cathode suffer from oxidation and deterioration at …

Surface Design with Cation and Anion Dual Gradient Stabilizes High‐Voltage LiCoO2

W Huang, Q Zhao, M Zhang, S Xu… - Advanced Energy …, 2022 - Wiley Online Library
LiCoO2 (LCO) is the most successful cathode material for commercial lithium‐ion batteries.
Cycling LCO to high potentials up to 4.5 V or even 4.6 V can significantly elevate the …