Water–solid contact electrification causes hydrogen peroxide production from hydroxyl radical recombination in sprayed microdroplets

B Chen, Y Xia, R He, H Sang… - Proceedings of the …, 2022 - National Acad Sciences
Contact electrification between water and a solid surface is crucial for physicochemical
processes at water–solid interfaces. However, the nature of the involved processes remains …

Emerging microdroplet chemistry for synthesis and analysis

X Yan - International Journal of Mass Spectrometry, 2021 - Elsevier
Recent studies have shown that remarkable reaction acceleration can be achieved at the
air/solution interface of microdroplets. The unique environment of microdroplets can drive …

Reaction acceleration promoted by partial solvation at the gas/solution interface

L Qiu, Z Wei, H Nie, RG Cooks - ChemPlusChem, 2021 - Wiley Online Library
The kinetics of organic reactions of different types in microvolumes (droplets, thin films, and
sealed tubes) show effects of gas/solution interfacial area, reaction molecularity and solvent …

Vessel effects in organic chemical reactions; a century-old, overlooked phenomenon

MM Nielsen, CM Pedersen - Chemical Science, 2022 - pubs.rsc.org
One of the most intriguing aspects of synthetic chemistry is the interplay of numerous
dependent and independent variables en route to achieve a successful, high-yielding …

Ammonium bicarbonate significantly accelerates the microdroplet reactions of amines with carbon dioxide

L Feng, X Yin, S Tan, C Li, X Gong, X Fang… - Analytical …, 2021 - ACS Publications
The reactions between amines and carbon dioxide (CO2) are among the most commonly
used and important carbon fixation reactions at present. Microdroplets generated by …

Is Reaction Acceleration of Microdroplet Chemistry Favorable to Controlling the Enantioselectivity?

B Zheng, Y Wu, L Xue, J Sun, J Liu… - The Journal of Organic …, 2023 - ACS Publications
Microdroplet chemistry has been proven to amazingly accelerate many chemical and
biological reactions in the past 2 decades. Current microdroplet accelerated reactions are …

Glass surface as strong base,'green'heterogeneous catalyst and degradation reagent

Y Li, KH Huang, NM Morato, RG Cooks - Chemical Science, 2021 - pubs.rsc.org
Systematic screening of accelerated chemical reactions at solid/solution interfaces has been
carried out in high-throughput fashion using desorption electrospray ionization mass …

Silica particles convert thiol-containing molecules to disulfides

Y Li, KW Kolasinski, RN Zare - Proceedings of the National …, 2023 - National Acad Sciences
Synthetic amorphous silica is a common food additive and a popular cosmetic ingredient.
Mesoporous silica particles are also widely studied for their potential use in drug delivery …

Two Faces of the Bi−O Bond: Photochemically and Thermally Induced Dehydrocoupling for Si−O Bond Formation

J Ramler, J Schwarzmann, A Stoy… - European Journal of …, 2022 - Wiley Online Library
The diorgano (bismuth) alcoholate [Bi ((C6H4CH2) 2S) OPh](1‐OPh) has been synthesized
and fully characterized. Stoichiometric reactions, UV/Vis spectroscopy, and (TD‐) DFT …

Catalyst‐Free Three‐Component Petasis Reactions Accelerated in Microdroplets: Reaction Optimization and Senstive Detection by Mass Spectrometry

X Jin, Y Wu, J Sun, J Liu, H Cheng - Analysis & Sensing, 2023 - Wiley Online Library
Due to their important roles in medicine, the product of the Petasis reaction has attracted
extensive interest in pharmaceutical, medical and chemical communities. Traditional three …