The addition of a B–H bond to an unsaturated bond (polarized or unpolarized) is a powerful
and atom-economic tool for the synthesis of organoboranes. In recent years, s-block …

The catalytic hydroboration of imines, nitriles, and carbodiimides is a powerful method of
preparing amines which are key synthetic intermediates in the synthesis of many value …

The continued development of hydroboration catalysts typifies the importance of this
transformation as a testbed for catalytic activity and as a fundamental reaction for organic …

Here, we describe the formation and use of silyl cobalt (III) dihydride complexes as powerful
catalysts for the hydrosilylation of a variety of imines starting from a low-valent well-defined …

Synthesis of Mesoionic N-Heterocyclic Olefins and Catalytic Application for Hydroboration
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Despite p-block clusters being known for over a century, their application as catalysts to
mediate organic transformations is underexplored. Here, the boron functionalized [P7] …

A convenient method for synthesizing aryl-containing trisubstituted alkenes through direct
alkylation of alkenes was successfully achieved under solvent-free and catalyst-free …

Abstract A stable O, N‐heterocyclic stannylene 1 bearing novel tetradentate 2, 4‐di‐tert‐
butyl‐6‐((2‐(1‐((pyridin‐2‐ylmethyl) imino) ethyl) phenyl) amino) phenolate ligand (RAPH2) …

In contrast to the recent reports on catalytic hydroboration of amides to amines with
pinacolborane (HBpin), a simple catalyst-free and solvent-free method for the hydroboration …

Eco-friendly zinc dihydrides stabilized by N-heterocyclic carbenes were demonstrated to be
highly efficient catalysts for the double hydroboration of nitriles with pinacolborane …