The properties of catenated nitrogen molecules, molecules containing internal chains of
bonded nitrogen atoms, is of fundamental scientific interest in chemical structure and …

Poly-nitrogen compounds have been considered as potential high energy density materials
for a long time due to the large number of energetic N–N or N= N bonds. In most cases high …

Various valuable properties of azoarenes (“azo dyes”), including their vivid colors and their
facile cis–trans photoisomerization, lead to their wide use in the chemical industry. As a …

The reaction of tetra (o‐tolyl) diborane (4) with organic azides afforded three different
compounds, diborylamines, diboryltriazenes, and B2‐hexazenes having a bicyclic B2N6 …

This paper describes a cooperative iron–thiolate catalyst Cp* Fe (1, 2-Ph2PC6H4S)(NCMe)(
Cp*–= C5Me5–,[1 (NCMe)]) for regioselective hydroboration of aryl epoxide by …

The formally CoIV carbene Co (OR) 2 ( CPh2) is formed upon the reaction of
diphenyldiazomethane with the cobalt bis (alkoxide) precursor Co (OR) 2 (THF) 2. Structural …

A catalyst system comprising Fe2 (OtBu) 6 and an N-heterocyclic carbene ligand enables
efficient syntheses of (hetero) biaryls from the reactions of aryl Grignard reagents with a …

Herein we describe the stoichiometric and catalytic carbene-transfer reactivity of iron (II)
alkoxide complexes with iodonium ylide precursors. Treatment of PhIC (CO2Me) 2 with …

Herein we report the synthesis of Cr imido complexes in bis (alkoxide) ligand environments
and their nitrene transfer reactivity with isocyanides. The reaction of Cr2 (OR) 4 (OR= OC t …

The iron bis (alkoxide) complex Fe (OR) 2 (THF) 2 (R= CtBu2Ph), 1, was found to have
strikingly different reactivity with various aryl azides, ArN3. Azides with methyl or ethyl …