Pd metal catalysts for cross-couplings and related reactions in the 21st century: a critical review

A Biffis, P Centomo, A Del Zotto, M Zecca - Chemical Reviews, 2018 - ACS Publications
Cross-couplings and related reactions are a class of highly efficient synthetic protocols that
are generally promoted by molecular Pd species as catalysts. However, catalysts based on …

Transition metal nanoparticles as nanocatalysts for Suzuki, Heck and Sonogashira cross-coupling reactions

M Ashraf, MS Ahmad, Y Inomata, N Ullah… - Coordination Chemistry …, 2023 - Elsevier
Transition metal (TM) catalyzed cross-coupling reactions are the utmost versatile and
reliable methods for the production of many industrially important fine chemicals. The …

Bimetallic monolayer catalyst breaks the activity–selectivity trade-off on metal particle size for efficient chemoselective hydrogenations

Q Guan, C Zhu, Y Lin, EI Vovk, X Zhou, Y Yang, H Yu… - Nature Catalysis, 2021 - nature.com
Particle size governs the geometric and electronic structure of metal nanoparticles (NPs),
shaping their catalytic performance. However, size-dependent entanglement in the …

Noble-metal-based high-entropy-alloy nanoparticles for electrocatalysis

X Huang, G Yang, S Li, H Wang, Y Cao, F Peng… - Journal of Energy …, 2022 - Elsevier
Since the two seminal papers were published independently in 2004, high-entropy-alloys
(HEAs) have been applied to structural and functional materials due to the enhanced …

Pd nanoparticles for C–C coupling reactions

A Balanta, C Godard, C Claver - Chemical Society Reviews, 2011 - pubs.rsc.org
The catalytic formation of C–C bonds is one of the most useful transformations in organic
synthesis. Over the last decade, the use of transition metal nanoparticles (NPs) in catalysis …

The Heck reaction as a sharpening stone of palladium catalysis

IP Beletskaya, AV Cheprakov - Chemical Reviews, 2000 - ACS Publications
Palladium catalysis has achieved the status of an indispensable tool for both common and
state-of-theart organic synthesis. Among basic types of palladium-catalyzed transformations …

Nanoparticles as recyclable catalysts: the frontier between homogeneous and heterogeneous catalysis

D Astruc, F Lu, JR Aranzaes - … Chemie International Edition, 2005 - Wiley Online Library
Interest in catalysis by metal nanoparticles (NPs) is increasing dramatically, as reflected by
the large number of publications in the last five years. This field,“semi‐heterogeneous …

Colorimetric and fluorescent Schiff base sensors for trace detection of pollutants and biologically significant cations: A review (2010–2021)

A Kumar, M Saini, B Mohan, M Kamboj - Microchemical Journal, 2022 - Elsevier
The colorimetric and fluorescent Schiff base sensors have proven to be powerful tools in the
detection of metal ions due to their simplicity, low cost, rapid photophysical response, high …

Carbon− carbon coupling reactions catalyzed by heterogeneous palladium catalysts

L Yin, J Liebscher - Chemical Reviews, 2007 - ACS Publications
Homogeneous palladium catalysis has gained enormous relevance in various coupling
reactions such as Heck, Stille, Suzuki, Sonogashira, and Buchwald-Hartwig reactions. Many …

On the nature of the active species in palladium catalyzed Mizoroki–Heck and Suzuki–Miyaura couplings–homogeneous or heterogeneous catalysis, a critical review

NTS Phan, M Van Der Sluys… - Advanced Synthesis & …, 2006 - Wiley Online Library
A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …