[HTML][HTML] Catalytic systems mimicking the [FeFe]-hydrogenase active site for visible-light-driven hydrogen production

J Amaro-Gahete, MV Pavliuk, H Tian, D Esquivel… - Coordination Chemistry …, 2021 - Elsevier
A global hydrogen economy could ensure environmentally sustainable, safe and cost-
efficient renewable energy for the 21st century. Solar hydrogen production through artificial …

Electrode integration of synthetic hydrogenase as bioinspired and noble metal-free cathodes for hydrogen evolution

A Zamader, B Reuillard, P Marcasuzaa… - ACS …, 2023 - ACS Publications
Diiron complexes mimicking the H-cluster of [FeFe]-hydrogenases have been extensively
studied as (electro-) catalysts for proton reduction under homogeneous conditions. The …

Barrier discharge ionization detector in gas chromatography: a review on applications

AF Lopes, TSM Fernandes… - Critical Reviews in …, 2023 - Taylor & Francis
The barrier discharge ionization detector (BID) is one of the latest detection technologies
used in gas chromatography (GC). 306 papers from 2012 to 2021 with GC-BID analyses …

Non‐Covalent Integration of a [FeFe]‐Hydrogenase Mimic to Multiwalled Carbon Nanotubes for Electrocatalytic Hydrogen Evolution

A Zamader, B Reuillard, J Pécaut… - … A European Journal, 2022 - Wiley Online Library
Surface integration of molecular catalysts inspired from the active sites of hydrogenase
enzymes represents a promising route towards developing noble metal‐free and …

Covalent versus noncovalent attachments of [FeFe]‑hydrogenase models onto carbon nanotubes for aqueous hydrogen evolution reaction

Y Gao, SJ Wang, Z Guo, YZ Wang, YP Qu… - Journal of Inorganic …, 2024 - Elsevier
In an effort to develop the biomimetic chemistry of [FeFe]‑hydrogenases for catalytic
hydrogen evolution reaction (HER) in aqueous environment, we herein report the …

Phosphite Bearing [(μ-ADT)RFe2(CO)6] (ADT = Azadithiolate) Moieties: A Tool for the Building of Multimetallic [FeFe]-Hydrogenase Mimics

A Torres, DJ Vicent, A Collado… - …, 2023 - ACS Publications
A new phosphite ligand having three [(μ-ADT) RFe2 (CO) 6](R= p-HOC6H4) moieties (2)
has been prepared in good yield by the reaction of complex [(μ-ADT) RFe2 (CO) 6](R= p …

Improving the Stability of Silicon Nanowires During Photoelectrochemical Hydrogen Generation with Zinc 1T‐Phase Molybdenum Disulfide

SM Younan, Z Li, MP Fairchild… - Advanced Materials …, 2022 - Wiley Online Library
Semiconductor photoelectrodes directly convert sunlight into stored chemical energy. In
photoelectrochemical (PEC) devices, this photoconversion process relies on the junction …

Variation of dithiolate bridges in carbon nanotube-attached diiron chelate compounds for electrocatalytic hydrogen evolution reaction

PH Zhao, B Jin, SJ Wang, D Wang, Y Guo… - Applied Surface Science, 2023 - Elsevier
In an effort to explore the effect of dithiolate bridges on the electrochemical hydrogen
evolution reaction (HER) performances of hydrogenase-inspired catalysts under fully …

Two Complementary Approaches to Silicon-Supported Soluble [FeFe]-Hydrogenase Mimics

S Aguado, DJ Vicent, L Casarrubios… - …, 2022 - ACS Publications
Two series of silicon-supported [(μ-SCH2) 2NRFe2 (CO) 6](R= p-OHC6H4, 3, and (CH2)
2OH, 4a, and (CH2) 5OH, 4b) hydrogenase mimics, as well as octamethylsilsesquioxane …

Novel bioinspired and biohybrid electrode materials for hydrogen production

A Zamader - 2023 - theses.hal.science
Hydrogenase enzymes were first discovered in the 1930s. The first report of {Fe2 (μ-S2)(CO)
6} based catalyst was reported in 1928 without any information of [FeFe] hydrogenases. The …