In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Over the past fifteen years or so, the study of f-element single-ion magnets (f-SIMs) has gone
from being a sub-discipline of molecular magnetism to an established field of research in its …

Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

An ab initio methodology for the first‐principle derivation of crystal‐field (CF) parameters for
lanthanides is described. The methodology is applied to the analysis of CF parameters in …

Single-molecule magnets are compounds that exhibit magnetic bistability caused by an
energy barrier for the reversal of magnetization (relaxation). Lanthanide compounds are …

Magnetic polyoxometalates: from molecular magnetism to molecular spintronics and
quantum computing - Chemical Society Reviews (RSC Publishing) DOI:10.1039/C2CS35205B …

Single-molecule magnets that contain one spin centre may represent the smallest possible
unit for spin-based computational devices. Such applications, however, require the …

Since the 1990s and the discovery of the first Single Molecule Magnets (SMMs), chemists
and physicists have been working in concert to elaborate such molecular systems and …

The high axiality and Ising exchange interaction efficiently suppress quantum tunneling of
magnetization of an asymmetric dinuclear DyIII complex, as revealed by combined …

Over the past decade, lanthanide compounds have become of increasing interest in the field
of Single Molecule Magnets (SMMs) due to the large inherent anisotropy of the metal ions …