Cyclopropanes, one of the most important strained rings, have gained much attention for
more than a century because of their interesting and unique reactivity. They not only exist in …

Donor‐acceptor cyclopropanes not only participate in a broad range of ring openings with
nucleophiles, electrophiles, radical and red‐ox agents, but also are excellent substrates for …

In this review, we present the recent advances in the synthesis and reactivity of
vinylcyclopropanes (VCPs). Various important methodologies involving ylides, carbenoid …

The interest in cyclopropane derivatives is caused by the facts that, first, the three-carbon
ring is present in quite a few natural and biologically active compounds and, second …

Halogen bonding (XB) has recently emerged as a promising noncovalent activation mode
that can be employed in catalysis. However, methodologies utilizing XB remain rare, and the …

We herein present a strain-release glycosylation method employing a rationally designed
ortho-2, 2-dimethoxycarbonylcyclopropylbenzyl (CCPB) thioglycoside donor. The donor is …

Chemical glycosylation methodologies for the preparation of the bioactive oligosaccharides
and glycoconjugates promise reliable access to these compounds as homogeneous …

Acylcyclopropanes are employed as useful donor–acceptor cyclopropanes that undergo
formal (4+ 2) cyclocondensation with N-unprotected 3-substituted indoles in the presence of …

This work highlights stellane's cage stability and derivatization opportunities. A diverse
range of building blocks were synthesized using modern synthesis protocols to demonstrate …

The utility of thiourea catalysis in selective glycosylation strategies has gained significant
momentum lately due to its versatility in hydrogen bonding or anionic recognition activation …