Kinetico-mechanistic studies on CX (X= H, F, Cl, Br, I) bond activation reactions on organoplatinum (II) complexes

M Crespo, M Martinez, SM Nabavizadeh… - Coordination Chemistry …, 2014 - Elsevier
The activation of Csingle bondX bonds in homogeneous systems is a relevant topic in
relation to important catalytic industrial processes involving organic substrates and …

Mechanistic studies into the oxidative addition of Co (I) complexes: combining electroanalytical techniques with parameterization

C Sandford, LR Fries, TE Ball, SD Minteer… - Journal of the …, 2019 - ACS Publications
The oxidative addition of organic electrophiles into electrochemically generated Co (I)
complexes has been widely utilized as a strategy to produce carbon-centered radicals when …

The history of organoplatinum chemistry in Iran: 40-year research

RB Aghakhanpour, S Paziresh… - Journal of the Iranian …, 2020 - Springer
This review article is based on the scientific investigations of Prof. Mehdi Rashidi during his
working years in Shiraz University, Chemistry Department, Organometallic Chemistry …

Mechanistic Investigation of the Nickel-Catalyzed Suzuki Reaction of N,O-Acetals: Evidence for Boronic Acid Assisted Oxidative Addition and an Iminium Activation …

KT Sylvester, K Wu, AG Doyle - Journal of the American Chemical …, 2012 - ACS Publications
The mechanism of a recently reported Suzuki coupling reaction of quinoline-derived allylic
N, O-acetals has been studied using a combination of structural, stereochemical, and kinetic …

Methyl-coenzyme M reductase from methanogenic archaea: isotope effects on the formation and anaerobic oxidation of methane

S Scheller, M Goenrich, RK Thauer… - Journal of the American …, 2013 - ACS Publications
The nickel enzyme methyl-coenzyme M reductase (MCR) catalyzes two important
transformations in the global carbon cycle: methane formation and its reverse, the anaerobic …

Oxidative addition of ethyl iodide to a dimethylplatinum (ii) complex: unusually large kinetic isotope effects and their transition-state implications

SM Nabavizadeh, S Habibzadeh, M Rashidi… - …, 2010 - ACS Publications
The mechanism of oxidative addition of ethyl iodide to [PtMe2 (2, 2′-bipyridine)], 1, has
been investigated by product analysis and by study of secondary deuterium kinetic isotope …

Oxidative addition of MeI to some cyclometalated organoplatinum (II) complexes: Kinetics and mechanism

SM Nabavizadeh, H Amini, F Jame… - Journal of …, 2012 - Elsevier
New cyclometalated platinum (II) complexes [PtMe (C^ N) L], 1, in which C^ N=
deprotonated 2-phenylpyridine (ppy), benzo [h] quinoline (bhq) or 2-(p-tolyl) pyridine (tpy) …

Secondary kinetic isotope effects in oxidative addition of benzyl bromide to dimethylplatinum (II) complexes

MD Aseman, M Rashidi, SM Nabavizadeh… - …, 2013 - ACS Publications
The secondary α-deuterium kinetic isotope effects (KIEs),(k H/k D) α, have been determined,
at different temperatures and in solvents having different polarities, for reaction of …

Reactivity of organoplatinum complexes containing appended alcohol functional groups: Activation of dioxygen and hydrogen peroxide

KA Thompson, C Kadwell, PD Boyle… - Journal of Organometallic …, 2017 - Elsevier
The oxidative addition reactions of platinum (II) complexes [PtMe 2 (RN= CH-2-C 5 H 4 N)],
especially when R= CH 2 CH 2 OH or CH 2 CH 2 CH 2 OH, have been studied. Both …

Reactivity and Mechanism in the Oxidative Addition of Allylic Halides to a Dimethylplatinum (II) Complex

SJ Hoseini, H Nasrabadi, SM Nabavizadeh… - …, 2012 - ACS Publications
The complex [PtMe2 (2, 2′-bipyridine)], 1, reacts with allyl chloride and allyl bromide, to
give [PtXMe2 (CH2CH CH2)(2, 2′-bipyridine)], 2, X= Cl; 3, X= Br, with 2-methylallyl …