Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

The surface science of nanocrystals

MA Boles, D Ling, T Hyeon, DV Talapin - Nature materials, 2016 - nature.com
All nanomaterials share a common feature of large surface-to-volume ratio, making their
surfaces the dominant player in many physical and chemical processes. Surface ligands …

The critical impacts of ligands on heterogeneous nanocatalysis: A review

L Lu, S Zou, B Fang - ACS Catalysis, 2021 - ACS Publications
Ligand utilization is a necessary and powerful technique for the colloidal synthesis of
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …

Surface coordination chemistry of metal nanomaterials

P Liu, R Qin, G Fu, N Zheng - Journal of the American Chemical …, 2017 - ACS Publications
Surface coordination chemistry of nanomaterials deals with the chemistry on how ligands
are coordinated on their surface metal atoms and influence their properties at the molecular …

Functionalization of hollow nanomaterials for catalytic applications: nanoreactor construction

W Zhu, Z Chen, Y Pan, R Dai, Y Wu… - Advanced …, 2019 - Wiley Online Library
Hollow nanomaterials have attracted a broad interest in multidisciplinary research due to
their unique structure and preeminent properties. Owing to the high specific surface area …

Fundamental aspects of alkyne semi-hydrogenation over heterogeneous catalysts

Z Wang, Q Luo, S Mao, C Wang, J Xiong, Z Chen… - Nano Research, 2022 - Springer
Alkyne semi-hydrogenation is extremely significant for the production of polymer-grade
ethylene and lots of fine chemicals in modern industry. Many efforts had been devoted to …

Removal and utilization of capping agents in nanocatalysis

Z Niu, Y Li - Chemistry of Materials, 2014 - ACS Publications
Capping agents are frequently used in colloidal synthesis to inhibit nanoparticle overgrowth
and aggregation as well as to control the structural characteristics of the resulted …

The role and fate of capping ligands in colloidally prepared metal nanoparticle catalysts

LM Rossi, JL Fiorio, MAS Garcia, CP Ferraz - Dalton Transactions, 2018 - pubs.rsc.org
Metal nanoparticles have received intense scientific attention in the field of catalysis. Precise
engineering of nanomaterials' size, shape and surface composition, including adsorbed …

Surface and interface control of noble metal nanocrystals for catalytic and electrocatalytic applications

B Wu, N Zheng - Nano Today, 2013 - Elsevier
Catalysis and electrocatalysis by noble metal (NM) nanomaterials is typically surface and
interface-sensitive. Effective surface and interface control over NM nanomaterials provides …

[HTML][HTML] Untangling the role of the capping agent in nanocatalysis: recent advances and perspectives

S Campisi, M Schiavoni, CE Chan-Thaw, A Villa - Catalysts, 2016 - mdpi.com
Capping agents (organic ligands, polymers, surfactants, etc.) are a basic component in the
synthesis of metal nanoparticles with controlled size and well-defined shape. However, their …