Molecular metal phosphonates

J Goura, V Chandrasekhar - Chemical reviews, 2015 - ACS Publications
The carboxylate ligand,[RCO 2]−, is one of the most versatile and hence also one of the most
ubiquitous ligands in coordination chemistry.(1-4) Although fairly simple coordination modes …

Insight into Synthesis, properties and applications of metal Phosphonates: Emphasis on catalytic activities

K Rathore, R Jangir - Inorganica Chimica Acta, 2024 - Elsevier
Metal phosphonates have been recognized as promising catalysts due to their unique
properties such as convenient synthesis routes, lower cost, tunable acidity and basicity, and …

On/off fluorescent chemosensor for selective detection of divalent iron and copper ions: molecular logic operation and protein binding

G Tamil Selvan, C Varadaraju, R Tamil Selvan… - ACS …, 2018 - ACS Publications
Here, naphthalene diamine-based β-diketone derivative (compound LH) was successfully
used as a dual signaling probe for divalent cations, Fe2+ and Cu2+ ions, in bimodal …

Molecular transition-metal phosphonates

V Chandrasekhar, T Senapati, A Dey, S Hossain - Dalton Transactions, 2011 - pubs.rsc.org
Molecular transition-metal phosphonates are of relatively recent origin and can be
assembled by several synthetic strategies. The nuclearity and the structure of the metal …

Steric effects of the initiator substituent position on the externally initiated polymerization of 2-Bromo-5-iodo-3-hexylthiophene

N Doubina, SA Paniagua, AV Soldatova… - …, 2011 - ACS Publications
Externally initiated polymerization of 2-bromo-3-hexyl-5-iodothiophene was attempted from
four aryl and thiophene based small molecule initiators functionalized with a phosphonate …

Hydrothermal Synthesis and Structural Characterization of Metal Organophosphonate Oxide Materials: Role of Metal-Oxo Clusters in the Self Assembly of Metal …

BK Tripuramallu, SK Das - Crystal growth & design, 2013 - ACS Publications
Two new metal organophosphonate oxide materials with formulas [CuII4CuI2 (L) 2 (2, 2′-
bpy) 6 (HPW12O40)] n· 4 n H2O (1) and [Cu (2, 2′-bpy) VO2 (OH)(H2L)] n (2) have been …

Mechanistic aspects for the formation of copper dimer bridged by phosphonic acid and extending its dimensionality by organic and inorganic linkers: synthesis …

BK Tripuramallu, S Mukherjee, SK Das - Crystal growth & design, 2012 - ACS Publications
Six new copper metal complexes with formulas [Cu (H2O)(2, 2′-bpy)(H2L)] 2· H4L· 4H2O
(1),[{Cu (H2O)(2, 2′-bpy)(H3L)} 2 (H2L)]· 2H2O (2),[Cu (H2O)(1, 10-phen)(H2L)] 2· 6H2O …

Tri-, Tetra-, and Hexanuclear Copper(II) Phosphonates Containing N-Donor Chelating Ligands: Synthesis, Structure, Magnetic Properties, and Nuclease Activity

V Chandrasekhar, T Senapati, EC Sanudo… - Inorganic …, 2009 - ACS Publications
Reaction of Cu (ClO4) 2· 6H2O with cyclopentyl phosphonic acid and 2, 2′-bipyridine (bpy)
in presence of triethylamine afforded a trinuclear compound [Cu3 (C5H9PO3) 2 (bpy) 3 …

Mechanistic Investigations on E–N Bond-Breaking and Ring Expansion for N-Heterocyclic Carbene Analogues Containing the Group 14 Elements (E)

MD Su - Inorganic Chemistry, 2014 - ACS Publications
The potential-energy surfaces for the ring-expansion reactions i Pr N (CH) 2N (i Pr) E:(Rea–
E)+ SiH2Ph2→ six-membered ring heterocyclcic product (E= C, Si, Ge, Sn, and Pb) and i Pr …

A flexible tris-phosphonate for the design of copper and cobalt coordination polymers: unusual cage array topology and magnetic properties

CI Yang, YT Song, YJ Yeh, YH Liu, TW Tseng, KL Lu - CrystEngComm, 2011 - pubs.rsc.org
The reaction of the flexible tris-phosphonate precursor benzene-1, 3, 5-tris (
methylenephosphonic acid)(H6btmp) with CuCl2· 2H2O in H2O under hydrothermal …