The halogen bond

G Cavallo, P Metrangolo, R Milani, T Pilati… - Chemical …, 2016 - ACS Publications
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …

Supramolecular assemblies on surfaces: nanopatterning, functionality, and reactivity

DP Goronzy, M Ebrahimi, F Rosei, Arramel, Y Fang… - ACS …, 2018 - ACS Publications
Understanding how molecules interact to form large-scale hierarchical structures on
surfaces holds promise for building designer nanoscale constructs with defined chemical …

Assembling molecular Sierpiński triangle fractals

J Shang, Y Wang, M Chen, J Dai, X Zhou, J Kuttner… - Nature …, 2015 - nature.com
Fractals, being “exactly the same at every scale or nearly the same at different scales” as
defined by Benoit B. Mandelbrot, are complicated yet fascinating patterns that are important …

Halogen bonding in two‐dimensional crystal engineering

J Teyssandier, KS Mali, S De Feyter - ChemistryOpen, 2020 - Wiley Online Library
Halogen bonds, which provide an intermolecular interaction with moderate strength and
high directionality, have emerged as a promising tool in the repertoire of non‐covalent …

Halogen bonding in polymer science: from crystal engineering to functional supramolecular polymers and materials

G Berger, J Soubhye, F Meyer - Polymer Chemistry, 2015 - pubs.rsc.org
Halogen bonding (XB) is commonly defined as a non-covalent bond where halogen atoms
(X= Cl, Br, I) function as electron acceptors. As an analogue of hydrogen bonding, halogen …

Extended halogen bonding between fully fluorinated aromatic molecules

S Kawai, A Sadeghi, F Xu, L Peng, A Orita, J Otera… - Acs Nano, 2015 - ACS Publications
Halogen bonding is a noncovalent interaction where an electrophilic cap on a halogen
atom, the so-called σ-hole, attracts a nucleophilic site on an adjacent molecule. The …

Engineering quantum states and electronic landscapes through surface molecular nanoarchitectures

I Piquero-Zulaica, J Lobo-Checa, ZMA El-Fattah… - Reviews of Modern …, 2022 - APS
Surfaces are at the frontier of every known solid. They provide versatile supports for
functional nanostructures and mediate essential physicochemical processes. Intimately …

Halogen bonds in 2D supramolecular self-assembly of organic semiconductors

R Gutzler, C Fu, A Dadvand, Y Hua, JM MacLeod… - Nanoscale, 2012 - pubs.rsc.org
Weak interactions between bromine, sulphur, and hydrogen are shown to stabilize 2D
supramolecular monolayers at the liquid–solid interface. Three different thiophene-based …

Bicomponent supramolecular architectures at the vacuum–solid interface

X Bouju, C Mattioli, G Franc, A Pujol… - Chemical …, 2017 - ACS Publications
This review aims at giving the readers the basic concepts needed to understand two-
dimensional bimolecular organizations at the vacuum–solid interface. The first part …

[HTML][HTML] Surface-confined alternating copolymerization with molecular precision by stoichiometric control

L Xing, J Li, Y Bai, Y Lin, L Xiao, C Li, D Zhao… - Nature …, 2024 - nature.com
Keen desires for artificial mimicry of biological polymers and property improvement of
synthesized ones have triggered intensive explorations for sequence-controlled …