This Review gives a comprehensive overview of the most topical weakly coordinating
anions (WCAs) and contains information on WCA design, stability, and applications. As an …

Is there anything resembling a truly noncoordinating anion? Would it not be great to be able
to prepare any crazy, beautiful, or simply useful cationic species that one has in mind, or has …

It has been 20 years since Rosenthal published his brief paper titled “The Myth of the Non-
Coordinating Anion”. 1 In this seminal work, he reviewed structural and spectroscopic data …

The possibility of obtaining frustrated Lewis pairs (FLPs) suitable for H2-activation based on
the Lewis acid B (Ohfip) 31 (Ohfip= OC (H)(CF3) 2) was investigated. In this context, the …

Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

An integrated approach to the control of Δ E 1/2 values, and therefore comproportionation
equilibria, through medium effects was delineated for multi-step redox reactions involving …

Certainly one of the first topics to come to mind on seeing the term “molecular
electrochemistry” is the subject of electron-transfer reactions. In most cases, a multistep …

Electroanalytical chemists and others are concerned not only with the application of new
and classical techniques to analytical problems, but also with the fundamental theoretical …

Density Functional calculations have been performed to calculate the one-electron oxidation
potential for ferrocene and the redox couples for a series of small transition metal …

Electrochemistry is a powerful tool for the study of oxidative electron-transfer reactions
(anodic processes). Since the 1960s, the electrolytes of choice for nonaqueous …