The synthesis of benzylboronates by photochemical homologation of boronic acids with N-
tosylhydrazones under basic conditions is described. The reaction involves the photolysis of …

The metal-catalyzed carbenoid-based N–H insertions of α-stabilized diazo compounds and
relative precursors serve as robust strategies for the formation of C–N bonds. However …

Fused-cyclopropane ring-containing γ-lactone compounds are versatile building blocks in
many fields, including the synthesis of biologically active compounds. Here, we report the …

Di-and triarylmethanes are an important class of compounds in many fields. Here, we report
an efficient light-induced arylation (alkylation) for the synthesis of diarylmethanes, bis …

In recent times, diaryliodonium reagents (DAIRs) have witnessed a resurgence as arylating
reagents, especially under photoinduced conditions. However, reactions proceeding …

We present a new [3+ 2] cycloaddition reaction between alkyl–acceptor diazoalkanes under
visible light irradiation. By employing easily accessible alkyl–acceptor-type diazoalkanes or …

A highly regioselective photocatalytic method to access a variety of biaryl motifs under metal-
free conditions has been developed. The organophotocatalyst is involved in π–π stacking …

Diazo compounds and their precursors represent an interesting chemical category for
organic synthesis. Particularly, N-tosylhydrazones have attracted attention for their easy …

Among the various strategies to achieve C (sp3)-C (sp3) bond formation, the direct
application of alkanes and ethers as coupling partners is an emerging and appealing …

Modern laboratory practices demand safer, efficient, and more green and sustainable
solutions, especially given the often dangerous nature of the chemicals used. This study …