1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Photoredox catalysis of organic reactions driven by iron has attracted substantial attention
throughout recent years, due to potential environmental and economic benefits. In this …

Alkoxy radicals are highly reactive species that have long been recognized as versatile
intermediates in organic synthesis. However, their development has long been impeded due …

Despite the rich photochemistry of 3d‐metal complexes, the utilization of excited‐state
reactivity of these compounds in organic synthesis has been historically overlooked. The …

The mainstream applications of visible‐light photoredox catalysis predominately involve
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …

Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Aryl halides are a fundamental motif in synthetic chemistry, playing a critical role in metal-
mediated cross-coupling reactions and serving as important scaffolds in drug discovery …

Light alkanes are natural organic carbon sources and widely distributed in nature.
Transforming them into value-added fine chemicals affords attractively economic and …

Efficient excited-state electron transfer between an iron (III) photosensitizer and organic
electron donors was realized with green light irradiation. This advance was enabled by the …