The first Ge (0)–Ge (II) germylone–germylene-paired Ge2 complex (L Si) 2Ge2 (4) and the
molecular Ge4 cluster (L Si) 2Ge4 (5) supported by the chelating carbanionic ortho-C, C …

The suitability of electron‐rich bis‐silylenes, specifically the neutral chelating [SiII (Xant) SiII]
ligand (SiII= PhC (NtBu) 2Si, Xant= 9, 9‐dimethylxanthene) and the anionic [SiII (NAcrid) …

This article intends to highlight and comprehensively summarize the recent developments in
the field of silylene–coinage metal chemistry. Recent years have witnessed exponential …

The bis (amidinato)-heavier tetrylenes E (bzamP) 2 (E= Ge (2a) and Sn (2b); bzamP= N-
isopropyl-N′-(diphenylphosphanylethyl) benzamidinate), which are equipped with one …

We present an approach for preparing chain-type unsaturated molecules with low oxidation
state Si (I) and Sb (I) supported by amidinato ligands that exploit to generate heavy …

We have prepared two new silylene–phosphine-based hybrid ligands Si {N (R) C6H4
(PPh2)}{PhC (N t Bu) 2}[R= TMS {trimethylsilyl}(1) and TBDMS {tert-butyldimethylsilyl}(2)] …

A successful selective reduction of X2B-Tip (Tip= 1, 3, 5-i Pr3-C6H2, X= I, Br) with KC8 and
Mg metal, respectively, in the presence of a hybrid ligand (C6H4 (PPh2) LSi) leads to a …

This work presents the different coordination nature of the bidentate ligand towards gold and
silver complexes. The reaction of 1 with AuClSMe2 in dichloromethane resulted in two gold …

This review article focuses on amidinatotetrylenes that potentially can (or have already
shown to) behave as bi‐or tridentate ligands because they contain at least one …

Herein, we report the stabilization of lithium‐ion as the source of lithium to use as a trans‐
metalation reagent [{PhC (NtBu) 2Si (tBu) Li} 2I (tBuN) 2CPh](1). The reaction of 3 …