Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …

Bimetallic catalysis represents an alternative paradigm for coupling chemistry that
complements the more traditional single-site catalysis approach. In this perspective, recent …

Transition metals can assemble to form multinuclear complexes by engaging in direct metal-
to-metal interactions. Metal–metal covalent bonds provide a large perturbation in electronic …

The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

Significant progress has been made in the past 10–15 years on the design, synthesis, and
properties of multimetallic coordination complexes with heterometallic metal–metal bonds …

An emerging area of homogeneous catalysis is the use of catalysts featuring two closely
associated metal sites. This approach complements the traditional focus on single‐site …

We recently reported a bis (imino) pyridine (or pyridine diimine, PDI) manganese
precatalyst,(Ph2PPrPDI) Mn (1), that is active for the hydrosilylation of ketones and …

Metal–metal multiple bonds have been an intense area of focus in inorganic chemistry for
many decades as a result of their fundamentally interesting bonding properties, as well as …

An evaluation of catalyst nuclearity effects in Ni-catalyzed alkyne oligomerization reactions
is presented. A dinuclear complex, featuring a Ni–Ni bond supported by a naphthyridine …

Single electron transfer from the ZrIIICo0 heterobimetallic complex (THF) Zr (MesNP i Pr2)
3Co–N2 (1) to benzophenone was previously shown to result in the isobenzopinacol …