Microreaction processes for synthesis and utilization of epoxides: A review

Z Yan, J Tian, K Wang, KDP Nigam, G Luo - Chemical Engineering Science, 2021 - Elsevier
Microreaction process is becoming an effective approach to intensify numerous chemical
reactions in the laboratory research and industrial production. In this review, the excellent …

Propylene epoxidation using molecular oxygen over copper-and silver-based catalysts: a review

J Teržan, M Huš, B Likozar, P Djinović - ACS catalysis, 2020 - ACS Publications
Propylene oxide (PO) is a versatile chemical, mainly used in the synthesis of polyurethane
plastics. Propylene epoxidation using molecular oxygen could replace the tedious current …

Insight into the Effect of Copper Substitution on the Catalytic Performance of LaCoO3-Based Catalysts for Direct Epoxidation of Propylene with Molecular Oxygen

J Lei, J Dai, KB Tan, J Huang, G Zhan… - … Sustainable Chemistry & …, 2021 - ACS Publications
Direct epoxidation of propylene to propylene oxide (PO) with molecular oxygen as the most
atomically economical route remains challenging due to the low PO yield. In this study, CuO …

Effect of Na, Cs and Ca on propylene epoxidation selectivity over CuOx/SiO2 catalysts studied by catalytic tests, in-situ XAS and DFT

J Teržan, M Huš, I Arčon, B Likozar, P Djinović - Applied Surface Science, 2020 - Elsevier
This research focuses on epoxidation of propylene over pristine, Na, Ca and Cs modified
CuO x/SiO 2 catalysts using O 2. The selectivity of the reaction is analyzed using a …

Enhanced Selectivity of the Propylene Epoxidation Reaction on a Cu Monolayer Surface via Eley‐Rideal Mechanism

AA Sangolkar, R Pawar - ChemPhysChem, 2022 - Wiley Online Library
The aerobic oxidation of propylene to selectively achieve propylene oxide (PO) is a
challenging reaction in catalysis. Therefore, an active catalyst which shows enhanced PO …

Multimetallic catalysts of RuO 2–CuO–Cs 2 O–TiO 2/SiO 2 for direct gas-phase epoxidation of propylene to propylene oxide

T Chukeaw, A Seubsai, P Phon-In, K Charoen… - RSC Advances, 2016 - pubs.rsc.org
RuO2–CuO/SiO2 catalysts doped with Cs2O and TiO2 were investigated for the direct gas
phase epoxidation of propylene to propylene oxide (PO) using molecular oxygen under …

Synthesis and characterization of novel Ti doped hexagonal mesoporous silica catalyst for nonenzymatic hydrogen peroxide oxidation

D Düzenli, Ö Sahin, HÇ Kazıcı, N Aktaş… - … and Mesoporous Materials, 2018 - Elsevier
A new electrocatalyst, Ti-HMS was successfully synthesized by sol-gel method employing Ti
source tetrabutyl orthotitanate (TBOT) and silica source tetraethyl orthosilicate (TEOS, 99 …

First-principles kinetic Monte Carlo modeling of propylene epoxidation on the Ti2CuO6/Cu (111) and Cu2O (111) surfaces

TT Xiao, RY Li, GC Wang - Applied Surface Science, 2022 - Elsevier
Direct propylene epoxidation by molecular oxygen is one of the most important commercial
selective oxidation reactions. Although the mixed metal oxide (Ti 2 CuO 6/Cu (1 1 1)) with …

A density functional theory study of propylene epoxidation on RuO2 (110) surface

DO Atmaca, D Düzenli, MO Ozbek, I Onal - Applied Surface Science, 2016 - Elsevier
Propylene epoxidation is investigated on RuO 2 (110) and oxygen added RuO 2-O ot (110)
surfaces by periodic DFT computational method. The desired product propylene oxide (PO) …

Direct epoxidation of propylene to propylene oxide over RuO2-CuO-NaCl-TeO2-MnOx/SiO2 catalysts

P Phon-in, A Seubsai, T Chukeaw, K Charoen… - Catalysis …, 2016 - Elsevier
Abstract Multi-metallic RuO 2-CuO-NaCl-TeO 2-MnO x/SiO 2 catalysts were investigated for
the epoxidation of propylene to propylene oxide (PO) using O 2 under atmospheric …