Phase-Dependence of Molecular Structures Arising from Weak London Dispersion Interactions

NW Mitzel, JH Lamm - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus The structures of molecules can be different in different phases. Intermolecular
forces, even those of weak noncovalent interactions (WNCIs), can lead to a preference for …

Light-activated intercluster conversion of an atomically precise silver nanocluster

A Jana, M Jash, AK Poonia, G Paramasivam… - ACS …, 2021 - ACS Publications
Noble metal nanoclusters protected with carboranes, a 12-vertex, nearly icosahedral boron–
carbon framework system, have received immense attention due to their different …

The Telluraboranes closo‐TeB5Cl5 and closo‐TeB11Cl11 with Exceptionally Long Body Diagonals: Synthetic and Bonding Motifs for Innovative Octahedral and …

W Keller, J Ballmann, MB Sárosi… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Six‐vertex closo‐TeB5Cl5 (1) and twelve‐vertex closo‐TeB11Cl11 (2)
telluraboranes have been prepared via co‐pyrolysis of B2Cl4 with TeCl4 in vacuo at …

Gas-phase equilibrium molecular structures and ab initio thermochemistry of anthracene and rubrene

AA Otlyotov, IY Kurochkin, Y Minenkov… - Physical Chemistry …, 2022 - pubs.rsc.org
Semi-experimental gas-phase structures of anthracene and rubrene (5, 6, 11, 12-
tetraphenyltetracene) were determined by means of gas electron diffraction (GED). The use …

Solid‐State and Gas‐Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates

M Reichel, B Krumm, YV Vishnevskiy… - Angewandte Chemie …, 2019 - Wiley Online Library
An improved synthesis of the simplest nitric acid ester, methyl nitrate, and a new synthesis of
fluoromethyl nitrate use the metathesis of the corresponding iodomethanes with silver …

Inverse Problems in Pump–Probe Spectroscopy

DS Tikhonov, D Garg, M Schnell - Photochem, 2024 - mdpi.com
Ultrafast pump–probe spectroscopic studies allow for deep insights into the mechanisms
and timescales of photophysical and photochemical processes. Extracting valuable …

Accurate single crystal and gas-phase molecular structures of acenaphthene: A starting point in the search for the longest C–C bond

YV Vishnevskiy, AA Otlyotov, JH Lamm… - Physical Chemistry …, 2023 - pubs.rsc.org
The molecular structure of acenaphthene has been determined experimentally in the gas
phase using gas electron diffraction intensities and literature-available rotational constants …

Molecular structure of 5, 10, 15, 20-tetrakis (4′-fluorophenyl) porphyrin by combined gas-phase electron diffraction/mass spectrometry experiment and DFT …

IY Kurochkin, AE Pogonin, AA Otlyotov… - Journal of Molecular …, 2020 - Elsevier
Abstract Molecular parameters of 5, 10, 15, 20-tetrakis (4′-fluorophenyl) porphyrin were
determined for the first time by gas-phase electron diffraction. Conformational preference …

Inter‐and Intramolecular Aryl–Aryl Interactions in Partially Fluorinated Ethylenedioxy‐bridged Bisarenes

JH Weddeling, YV Vishnevskiy… - … A European Journal, 2020 - Wiley Online Library
Several ethylenedioxy‐bridged bisarenes with a variety of type and number of aryl groups
were synthesized to study non‐covalent dispersion‐driven inter‐and intramolecular aryl …

Structures and internal dynamics of diphenylether and its aggregates with water

M Fatima, D Maué, C Pérez, DS Tikhonov… - Physical Chemistry …, 2020 - pubs.rsc.org
We report on a detailed multi-spectroscopic analysis of the structures and internal dynamics
of diphenylether and its aggregates with up to three water molecules by employing …