Biocatalytic reduction reactions from a chemist's perspective

F Hollmann, DJ Opperman… - Angewandte Chemie …, 2021 - Wiley Online Library
Reductions play a key role in organic synthesis, producing chiral products with new
functionalities. Enzymes can catalyse such reactions with exquisite stereo‐, regio‐and …

Before enzymes and templates: theory of surface metabolism

G Wächtershäuser - Microbiological reviews, 1988 - Am Soc Microbiol
Woese's three kingdoms (161-166) constitute the deepest branching of the known
biosphere. His suggestion to search for a common ancestor has led to the present …

Enzymatic reductions for the chemist

F Hollmann, IWCE Arends, D Holtmann - Green Chemistry, 2011 - pubs.rsc.org
When challenged by a difficult reduction reaction, a chemist should always also consider
biocatalysis in synthesis planning. The inherent selectivity of enzymes has been known for …

Syngas fermentation: a microbial conversion process of gaseous substrates to various products

JR Phillips, RL Huhnke, HK Atiyeh - Fermentation, 2017 - mdpi.com
Biomass and other carbonaceous materials can be gasified to produce syngas with high
concentrations of CO and H2. Feedstock materials include wood, dedicated energy crops …

[HTML][HTML] A review of conversion processes for bioethanol production with a focus on syngas fermentation

M Devarapalli, HK Atiyeh - Biofuel Research Journal, 2015 - biofueljournal.com
Bioethanol production from corn is a well-established technology. However, emphasis on
exploring non-food based feedstocks is intensified due to dispute over utilization of food …

Benzoyl‐coenzyme A reductase (dearomatizing), a key enzyme of anaerobic aromatic metabolism: ATP dependence of the reaction, purification and some properties …

M Boll, G Fuchs - European journal of biochemistry, 1995 - Wiley Online Library
Anoxic metabolism of many aromatic compounds proceeds via the common intermediate
benzoyl‐CoA. Benzoyl‐CoA is dearomatized by benzoyl‐CoA reductase (dearomatizing) in …

Alcohol production through volatile fatty acids reduction with hydrogen as electron donor by mixed cultures

KJJ Steinbusch, HVM Hamelers, CJN Buisman - Water research, 2008 - Elsevier
In this research we demonstrated a new method to produce alcohols. It was experimentally
feasible to produce ethanol, propanol and butanol from solely volatile fatty acids (VFAs) with …

Synthesis gas as substrate for the biological production of fuels and chemicals

JR Phillips, EC Clausen, JL Gaddy - Applied biochemistry and …, 1994 - Springer
Synthesis gas provides a simple substrate for the production of fuels and chemicals.
Synthesis gas can be produced via established technologies from a variety of feedstocks …

Single gene insertion drives bioalcohol production by a thermophilic archaeon

M Basen, GJ Schut, DM Nguyen… - Proceedings of the …, 2014 - National Acad Sciences
Bioethanol production is achieved by only two metabolic pathways and only at moderate
temperatures. Herein a fundamentally different synthetic pathway for bioalcohol production …

Biocatalytic reduction of carboxylic acids

K Napora‐Wijata, GA Strohmeier… - Biotechnology …, 2014 - Wiley Online Library
An increasing demand for non‐petroleum‐based products is envisaged in the near future.
Carboxylic acids such as citric acid, succinic acid, fatty acids, and many others are available …