The fabrication strategies of near-infrared absorbing transition metal complexes

J Shen, W He - Coordination Chemistry Reviews, 2023 - Elsevier
The fluorophores with absorption and emission in the near-infrared region have attracted
increased attention and are widely used for bioimaging and phototherapy with high …

Radical versus nonradical states of azobis (benzothiazole) as a function of ancillary ligands on selective ruthenium platforms

A Singh, S Dey, S Panda, GK Lahiri - Inorganic Chemistry, 2021 - ACS Publications
The paper deals with the electronic impact of ancillary ligands on the varying redox features
of azobis (benzothiazole)(abbt) in the newly introduced mononuclear ruthenium complexes …

Inner-sphere electron transfer at the ruthenium-azo interface

S Panda, A Singh, S Dey, KW Huang, GK Lahiri - Dalton Transactions, 2022 - pubs.rsc.org
Metal complexes exhibiting multiple reversible redox states have drawn continuing research
interest due to their electron reservoir features. In this context, the present article describes …

Fine Tuning between Radical versus Nonradical States of Azoheteroarenes on Selective Osmium Platforms

L Seikh, S Dhara, A Shukla, A Singh… - Inorganic …, 2024 - ACS Publications
The article highlights the cooperative impact of azoheteroarenes [abbt: 2, 2′-azobis
(benzothiazole), L1–L3; bmpd:(E)-1, 2-bis (1-methyl-1 H-pyrazole-3-yl) diazene, L4] and …

Diruthenium and triruthenium compounds of the potential redox active non-chelated η 1-N, η 1-N-benzothiadiazole bridge

S Dey, AS Hazari, SM Mobin, GK Lahiri - Dalton Transactions, 2022 - pubs.rsc.org
In the present study, a series of non-chelated BTD (2, 1, 3-benzothiadiazole)-bridged
diruthenium (II)([{(CH3CN)(acac) 2RuII} 2 (μ-BTD)] 1,[{CH3CN (acac) 2RuII}(μ-BTD){RuII …

Hydroquinone/quinone electro-and photochemical interconversion in isolable polypyridylruthenium (ii) complexes

D Oyama, T Kanno, T Takase - Dalton Transactions, 2021 - pubs.rsc.org
Quinone derivatives and their metal complexes are well-known molecules that participate in
electron-transfer reactions relevant to diverse fields. However, the fundamental knowledge …

Unusually Strong Long-range Electronic Coupling Across Redox-Active Bridges in M3+/M4+ Mixed-Valence Complexes of Group 4 Congeners

CS Bell, NJ DeYonker, CE Moore, KM Clark - 2021 - chemrxiv.org
Homobimetallic complexes of Group 4 metals, supported by the redox-active tetrakis (imino)
pyracene (TIP) ligand were synthesized and isolated. The formation of these complexes …

Ligand-Bridged Bis (Styryl Ruthenium) Complexes: Structural Isomerism and Aspects of Electron Delocalization in Their Mixed-Valent States

N Rotthowe - 2021 - kops.uni-konstanz.de
Compounds containing the quinoid motif, which can be understood as the two-
electronoxidation product of phenols, are plenty, both in natur e 105 and in materials …

Redox‐Switchable Catalysis

NI Regenauer, JS Doll… - Encyclopedia of Inorganic …, 2011 - Wiley Online Library
The ability to control catalytic properties, such as selectivity and rate during the reaction,
represents an attractive tool which can potentially deliver the synthesis of specialized …