C–C bond forming cross-couplings are convenient technologies for the construction of
functional molecules. Consequently, there is continual interest in approaches that can …

Transannular reactions have shown a remarkable performance for the construction of
polycyclic scaffolds from medium-or large-sized cyclic molecules in an unconventional …

The divergent catalytic reactions based on C–C activation of benzocyclobutenones have
been discovered, consisting of a highly enantioselective dearomatic “Cut & Sew” …

Abstract Transition‐metal‐catalyzed [4+ 4] cycloaddition leading to cyclooctanoids has
centered on dimerization between 1, 3‐diene‐type substrates. Herein, we describe a [4σ+ …

Reported here is the Rh and Zn cocatalyzed [4+ 2] cycloaddition of newly designed yne-
vinylcyclobutanones, which can generate 5/6 or 6/6 bicyclic products with an all-carbon …

The first enantioselective total syntheses of (−)-caulamidine D (5) and (−)-isocaulamidine D
(6) were accomplished. Their absolute configurations were unambiguously elucidated …

Here, we describe a transition-metal-free condition that realized the intramolecular
acylfluorination of unactivated olefins. It was designed to access seven-membered-ring …

Transition metal‐catalyzed annulations of four‐membered rings via C− C activation are
powerful tools to construct complex fused and bridged ring systems. Despite significant …

A reverse concerted metalation–deprotonation (CMD) process has been proposed as a key
step to rationalize our newly discovered Rh-catalyzed C–C/Colefin–H cascade reaction to …

The first Ru (II)-catalyzed cascade C–H activation/annulation reactions of N-aryl-
pyrazolidinones with sulfoxonium ylides for the synthesis of cinnoline-fused pyrazolidinones …