Abstract The Friedel‐Crafts reaction stands as a powerful synthetic tool for C− H
functionalization of aromatic feedstocks, which is conventionally realized through …

Axially chiral architectures exist widely in natural products, biologically relevant molecules,
chiral ligands and catalysts as well as functional materials. Therefore, catalytic asymmetric …

An efficient catalytic asymmetric electrophilic sulfenylation reaction for the synthesis of
planar‐chiral sulfur‐containing cyclophanes has been developed for the first time. This was …

We herein introduce biarylhemiboronic esters as a new type of bridged biaryl reagent for
asymmetric synthesis of axially chiral biaryl structures, and the palladium-catalyzed …

Axially chiral carboxylic acids are important motifs in chiral catalysts and ligands. We herein
reported the synthesis of axially chiral carboxylic acids via Pd (II)-catalyzed atroposelective …

Axially chiral biaryl compounds are ubiquitous scaffolds in natural products, bioactive
molecules, chiral ligands and catalysts, but biocatalytic methods for their asymmetric …

Upgrading CO2 to value‐added chiral molecules via catalytic asymmetric C− C bond
formation is a highly important yet challenging task. Although great progress on the …

Herein we present an efficient chiral phosphoric-acid-catalyzed atropoenantioselective
asymmetric reductive amination of biaryl dialdehydes. The process involves …

Atropisomers have attracted a great deal of attention lately due to their numerous
applications in organic synthesis and to their employment in drug discovery. However, the …

A dynamic thermodynamic resolution method for converting (R/S)-BINOL (1, 1′-binaphthyl-
2, 2′-diol) into (R)-BINOL in 100% theoretical yield is reported. This technique involves …