Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Photo‐iniferter RAFT polymerization

M Hartlieb - Macromolecular Rapid Communications, 2022 - Wiley Online Library
Light‐mediated polymerization techniques offer distinct advantages over polymerization
reactions fueled by thermal energy, such as high spatial and temporal control as well as the …

Polymerization techniques in polymerization-induced self-assembly (PISA)

C Liu, CY Hong, CY Pan - Polymer Chemistry, 2020 - pubs.rsc.org
The development of controlled/“living” polymerization greatly stimulated the prosperity of the
fabrication and application of block copolymer nano-objects. Controlled/“living” …

Up in the air: oxygen tolerance in controlled/living radical polymerisation

J Yeow, R Chapman, AJ Gormley… - Chemical Society Reviews, 2018 - pubs.rsc.org
The requirement for deoxygenation in controlled/living radical polymerisation (CLRP) places
significant limitations on its widespread implementation by necessitating the use of large …

Machine-Learning-Guided Discovery of 19F MRI Agents Enabled by Automated Copolymer Synthesis

M Reis, F Gusev, NG Taylor, SH Chung… - Journal of the …, 2021 - ACS Publications
Modern polymer science suffers from the curse of multidimensionality. The large chemical
space imposed by including combinations of monomers into a statistical copolymer …

Photoinitiated Polymerization‐Induced Self‐Assembly (Photo‐PISA): New Insights and Opportunities

J Yeow, C Boyer - Advanced Science, 2017 - Wiley Online Library
The polymerization‐induced self‐assembly (PISA) process is a useful synthetic tool for the
efficient synthesis of polymeric nanoparticles of different morphologies. Recently, studies on …

PET-RAFT polymerisation: towards green and precision polymer manufacturing

J Phommalysack-Lovan, Y Chu, C Boyer… - Chemical …, 2018 - pubs.rsc.org
The necessity of sustainable development in the chemical industry has continuously drawn
attention to find safe, environmentally friendly and atom-economic chemical processes …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

Recent advances on photobleachable visible light photoinitiators of polymerization

F Dumur - European Polymer Journal, 2023 - Elsevier
Photopolymerization under visible light has known major breakthroughs in recent years due
to the development of new irradiation setups based on Light-Emitting Diodes (LEDs) …

Oxygen tolerant photopolymerization for ultralow volumes

J Yeow, R Chapman, J Xu, C Boyer - Polymer Chemistry, 2017 - pubs.rsc.org
A benchtop approach is developed for the synthesis of various polymeric architectures using
an aqueous Reversible Addition–Fragmentation chain Transfer (RAFT) photopolymerization …