Poly‐and perfluorinated chemicals, including perfluorinated alkyl substances (PFAS), are
pervasive in today's society, with a negative impact on human and ecosystem health …

Spin-center shift (SCS) is a radical process involving 1, 2-radical translocation along with a
two-electron ionic movement, such as elimination of an adjacent leaving group. Such a …

Microbial response to toxic fluoride anion has traditionally been studied by adding inorganic
fluoride salts to growth media. Fluoride is known to spontaneously transit the membrane as …

The copper radical oxidases (CROs) are an evolutionary and functionally diverse group of
enzymes established by the historically significant galactose 6-oxidase and glyoxal oxidase …

The concept of genetic code expansion (GCE) has revolutionized the field of chemical and
synthetic biology, enabling the site-specific incorporation of noncanonical amino acids …

Copper radical oxidases (CROs) from Auxiliary Activity Family 5, Subfamily 2 (AA5_2), are
organic cofactor-free biocatalysts for the selective oxidation of alcohols to the corresponding …

Besides proteins and nucleic acids, carbohydrates are also ubiquitous building blocks of
living systems. Approximately 70% of mammalian proteins are glycosylated. Glycans not …

The heme-dependent l-tyrosine hydroxylases (TyrHs) in natural product biosynthesis
constitute a new enzyme family in contrast to the nonheme iron enzymes for DOPA …

Developing highly efficient catalytic protocols for C–sp (3)–H bond aerobic oxidation under
mild conditions is a long-desired goal of chemists. Inspired by nature, a biomimetic …

Hydroxymethylfurfural (HMF) can be oxidized to 2, 5-diformylfuran (DFF) by galactose
oxidase (GO) with H 2 O 2 as the byproduct. The active site of GO is composed of the ECu …