Investigating the Local Structure of Lanthanoid Hafnates Ln2Hf2O7 via Diffraction and Spectroscopy

PER Blanchard, S Liu, BJ Kennedy… - The Journal of …, 2013 - ACS Publications
The lanthanoid hafnates Ln2Hf2O7 (Ln= La, Pr, Nd, Sm–Tm) were studied using a
combination of synchrotron X-ray and neutron powder diffraction together with X-ray …

Structural assessment and irradiation response of La2Zr2O7 pyrochlore: impact of irradiation temperature and ion fluence

A Panghal, Y Kumar, PK Kulriya, PM Shirage… - Journal of Alloys and …, 2021 - Elsevier
Highlights•We irradiated the La 2 Zr 2 O 7 pyrochlore using 1 MeV Xe 4+ ions at~ 88 K and
300 K.•Damage increases with ion fluence at both temperatures and is significantly higher …

An ultrafast rechargeable and high durability lithium metal battery using composite electrolyte with the three-dimensional inorganic framework by Li6. 4La3Zr1. 4Ta0 …

H Liu, M Zhao, X Bai, P Wang, X Wang, J Li - ETransportation, 2023 - Elsevier
The liquid electrolyte used in traditional lithium-ion batteries has risks of leakage,
combustion and explosion. Solid electrolyte is one of the effective strategies to solve the …

Physical insights into the grain size effect on the electrical properties of nanocrystalline La2Zr2O7 pyrochlores

C Kaliyaperumal, SK Marndi, A Sankarakumar… - Ceramics …, 2023 - Elsevier
The role of grain size on the electrical properties of nanocrystalline La 2 Zr 2 O 7 (LZO)
ceramics prepared by chemical co-precipitation is reported. Grain size from 10 to 70 nm was …

Heavy-ion irradiation effects of Gd2Zr2O7 nanocrystalline ceramics as nuclear waste immobilization matrix

K Liu, K Zhang, T Deng, B Luo, H Zhang - Journal of Nuclear Materials, 2020 - Elsevier
In this study, the irradiation response of Gd 2 Zr 2 O 7 nanocrystalline ceramic was
systematically studied under 5 MeV Xe 20+ with radiation dose ranging from 2.6 dpa to 20.4 …

Comparative neutron and X-ray diffraction analysis of anionic and cationic ordering in rare-earth zirconates (Ln= La, Nd, Tb, Yb, Y)

AA Yastrebtsev, VV Popov, AP Menushenkov… - Journal of Alloys and …, 2020 - Elsevier
The influence of the cation radii ratio (γ= 1.37–1.61) and temperature of the isothermal
annealing on the specific features of fluorite–pyrochlore phase transition in Ln 2 O 3: ZrO 2 …

Evidence for percolation diffusion of cations and reordering in disordered pyrochlore from accelerated molecular dynamics

R Perriot, BP Uberuaga, RJ Zamora, D Perez… - Nature …, 2017 - nature.com
Diffusion in complex oxides is critical to ionic transport, radiation damage evolution,
sintering, and aging. In complex oxides such as pyrochlores, anionic diffusion is dramatically …

Utilizing non-stoichiometry in Nd 2 Zr 2 O 7 pyrochlore: exploring superior ionic conductors

P Anithakumari, V Grover, C Nandi, K Bhattacharyya… - RSC …, 2016 - pubs.rsc.org
To explore materials with high ionic conductivity without any heterovalent substitution, a non-
stoichiometric Nd2− xZr2+ xO7+ x/2 (− 0.2≤ x≤ 0.4) pyrochlore system was synthesized via …

Induced oxygen vacancies and their effect on the structural and electrical properties of a fluorite-type CaZrO 3–Gd 2 Zr 2 O 7 system

V Thampi, PR Padala, AN Radhakrishnan - New Journal of Chemistry, 2015 - pubs.rsc.org
Solid oxide materials were prepared via a solid state reaction route with a stoichiometry
composition: x% of CaZrO3 and (100− x)% of Gd2Zr2O7 (x= 10, 20, 33.3, 40). Powder X-ray …

Alpha-particle irradiation effects on uranium-bearing Gd2Zr2O7 ceramics for nuclear waste forms

X Shu, L Fan, Y Xie, W Zhu, S Pan, Y Ding, F Chi… - Journal of the European …, 2017 - Elsevier
It is necessary to study the self-irradiation effects of nuclear waste forms under α-decay in
the long term storage. In the present work, accelerated irradiation experiments were …