Reversible Radical Addition Guides Selective Photocatalytic Intermolecular Thiol‐Yne‐Ene Molecular Assembly

NS Shlapakov, AD Kobelev, JV Burykina… - Angewandte Chemie …, 2024 - Wiley Online Library
In modern organic chemistry, harnessing the power of multicomponent radical reactions
presents both significant challenges and extraordinary potential. This article delves into this …

Redox-Paired Reductive Heck Reaction and Oxidative Esterification Catalyzed by Mesoionic Carbenes

B Huang, Z Zhang, J Jiao, W Liu, X Yan - Organic Letters, 2024 - ACS Publications
Paring a reductive reaction and an oxidative reaction in one reaction could be immensely
important in achieving atom economic and environmental advantages. Herein, we report a …

Anti-selective Cyclopropanation of Nonconjugated Alkenes with Diverse Pronucleophiles via Directed Nucleopalladation

HQ Ni, TM Alturaifi, W Rodphon… - Journal of the …, 2024 - ACS Publications
A facile approach to obtaining densely functionalized cyclopropanes is described. The
reaction proceeds under mild conditions via the directed nucleopalladation of …

Palladium-Catalyzed Carbohalogenation of Olefins with Alkynyl Oxime Ethers: Rapid Access to Chlorine-Containing Isoxazoles

L Zhang, C Hong, J Tang, W Wu… - The Journal of Organic …, 2024 - ACS Publications
A palladium-catalyzed carbohalogenation of olefins with alkynyl oxime ethers has been
described, which provides efficient and practical access to various chlorine-containing …

Palladium-Catalyzed 1, 2-Alkynylarylation of Vinyl Arenes with Haloalkynes and Arylboronic Acids

R Ma, S Fang, H Jiang, W Wu - Organic Letters, 2024 - ACS Publications
We herein disclose a novel palladium-catalyzed 1, 2-alkynylarylation of vinyl arenes using
haloalkynes and arylboronic acids as coupling partners. This reaction is characterized by …

Electrochemically enabled (3+ 2) cycloaddition of unbiased alkenes and β-dicarbonyls

SM Suryawanshi, S Sahoo, PS Shaligram… - Chemical …, 2024 - pubs.rsc.org
A (3+ 2) cycloaddition between unbiased alkenes and 1, 3-dicarbonyls is accomplished by
judicious choice of electrode material and electrocatalyst to access dihydrofuran derivatives …

Electrochemical Oxidative Sulfonylation–Azidation of Alkenes

B Song, P Gao, B Hu, C Zhang - The Journal of Organic Chemistry, 2024 - ACS Publications
A novel electrochemical oxidative sulfonylation–azidation of alkenes is accomplished by
using sulfonyl hydrazide and trimethylsilyl azide (TMSN3) for the one-pot and green …

[HTML][HTML] Theoretical Investigations of Para-Methoxystyrene/Styrene Polymerization Catalyzed by Cationic Methyl- and Dibenzobarrelene-Based α-Diimine Palladium …

L Zhu, Y Luo, X Wen, W Zhang, G Zhou - Inorganics, 2024 - mdpi.com
The polymerization mechanism of para-methoxystyrene catalyzed by cationic α-diimine
palladium complexes with various ancillary ligands was rigorously examined using density …