Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐or
alkenyl‐metal reagents, which have a wide range of applications in organic transformations …

This review presents the catalytic application of Schiff Base in different chemical reactions.
Schiff base ligands consist of imine (-C= N-) functional group derived from the condensation …

Hydrosilylation reactions, the (commonly) anti-Markovnikov additions of silanes to
unsaturated bonds present in compounds such as alkenes and alkynes, offer numerous …

Hydrosilylation is a valuable approach for the construction of organosilanes, which are
precursors to silicone materials that are widely incorporated in our everyday lives. The …

Geminal bis (silanes) are versatile synthetic building blocks owing to their stability and
propensity to undergo a variety of transformations. However, the scarcity of catalytic methods …

The amino imidazolin-2-imine ligand [HAmIm, 1, 2-(DippNH)–C6H4–N═ C (N i PrCMe) 2] is
employed in the synthesis of the paramagnetic cobalt (I) arene complex Co (AmIm)(η 6 …

Hydrosilylation of alkenes is an important process in the synthesis of organosilicon
compounds in which an Si–H species is added across a carbon–carbon double bond (C …

The dimeric β-diketiminate manganese hydride compound,[(2, 6-iPr2PhBDI) Mn (μ-H)] 2,
was prepared by treating [(2, 6-iPr2PhBDI) Mn (μ-Cl)] 2 with NaEt3BH. This compound was …

Hydrosilylation of alkynes generally yield vinylsilanes, which are inert to the further
hydrosilylation because of the steric effects. Reported here is the first successful …

We report a simple and effective nickel-based catalytic system, NiCl2· 6H2O/t BuOK, for the
electrophilically activated hydrosilylation of terminal alkenes with primary silanes. This …