Mixed-valence clusters: Prospects for single-molecule magnetoelectrics

A Palii, S Aldoshin, B Tsukerblat - Coordination Chemistry Reviews, 2021 - Elsevier
In this review we summarize the results of recent studies of the mechanisms of
magnetoelectric effect in mixed-valence molecules. Consideration of fairly different systems …

Hybrid molecular magnets with lanthanide-and countercation-mediated interfacial electron transfer between phthalocyanine and polyoxovanadate

I Werner, J Griebel, A Masip-Sánchez, X López… - Inorganic …, 2022 - ACS Publications
A series of {V12}-nuclearity polyoxovanadate cages covalently functionalized with one or
sandwiched by two phthalocyaninato (Pc) lanthanide (Ln) moieties via V–O–Ln bonds were …

Quantum coherent spin–electric control in a molecular nanomagnet at clock transitions

J Liu, J Mrozek, A Ullah, Y Duan, JJ Baldoví… - Nature Physics, 2021 - nature.com
Electrical control of spins at the nanoscale offers significant architectural advantages in
spintronics, because electric fields can be confined over shorter length scales than magnetic …

Addressing multiple resistive states of polyoxovanadates: conductivity as a function of individual molecular redox states

O Linnenberg, M Moors… - Journal of the …, 2018 - ACS Publications
The sustainable development of IT-systems requires a quest for novel concepts to address
further miniaturization, performance improvement, and energy efficiency of devices. The …

Redox-induced gating of the exchange interactions in a single organic diradical

R Gaudenzi, J De Bruijckere, D Reta, IPR Moreira… - ACS …, 2017 - ACS Publications
Embedding a magnetic electroactive molecule in a three-terminal junction allows for the fast
and local electric field control of magnetic properties desirable in spintronic devices and …

Electric control of spin transitions at the atomic scale

P Kot, M Ismail, R Drost, J Siebrecht, H Huang… - Nature …, 2023 - nature.com
Electric control of spins has been a longstanding goal in the field of solid state physics due
to the potential for increased efficiency in information processing. This efficiency can be …

New pronounced progress in the synthesis of group 5 polyoxometalates

J Dopta, LK Mahnke, W Bensch - CrystEngComm, 2020 - pubs.rsc.org
The chemistry of polyoxomolybdates and polyoxotungstates has been systematically
developed since their first discovery more than 100 years ago. In contrast, significant …

Modelling the properties of magnetic clusters with complex structures: how symmetry can help us

B Tsukerblat, A Palii, JM Clemente-Juan… - … Reviews in Physical …, 2020 - Taylor & Francis
The purpose of this article is to answer the question of how symmetry helps us to investigate
and understand the properties of nanoscopic magnetic clusters with complex structures. The …

Single ion magnets based on lanthanoid polyoxomolybdate complexes

JJ Baldoví, Y Duan, C Bustos, S Cardona-Serra… - Dalton …, 2016 - pubs.rsc.org
Polyoxometalate (POM) chemistry has recently offered excellent examples of single ion
magnets (SIMs) and molecular spin qubits. Compared with conventional coordination …

Organic mixed-valence compounds and the overhauser effect in insulating solids

S Pylaeva, P Marx, G Singh, TD Kühne… - The Journal of …, 2021 - ACS Publications
Recent experiments have shown that the organic free radical 1, 3-bisdiphenylene-2-
phenylallyl (BDPA) can induce an Overhauser effect dynamic nuclear polarization in …