Method to derive the infrared complex refractive indices n (λ) and k (λ) for organic solids from KBr pellet absorption measurements

KA Peterson, RM Francis, CA Banach, AM Bradley… - Applied Optics, 2024 - opg.optica.org
Obtaining the complex refractive index vectors n (ν~) and k (ν~) allows calculation of the
(infrared) reflectance spectrum that is obtained from a solid in any of its many morphological …

Optimal spectral resolution for infrared studies of solids and liquids

BM Forland, KD Hughey, MJ Wilhelm… - Applied …, 2024 - journals.sagepub.com
Due to a legacy originating in the limited capability of early computers, the spectroscopic
resolution used in Fourier transform infrared spectroscopy and other systems has largely …

Solid phase characterization and transformation of illite mineral with gas-phase ammonia treatment

SA Di Pietro, HP Emerson, YP Katsenovich… - Journal of Hazardous …, 2022 - Elsevier
In situ remediation applications of ammonia (NH 3) gas have potential for sequestration of
subsurface contamination. Ammonia gas injections initially increase the pore water pH …

Combining spectroscopic techniques to determine the optical constants of powdered lactose

MO Yokosuk, TE Tiwald, DL Saunders, TA Blake… - Applied Optics, 2021 - opg.optica.org
A method for deriving the optical constants (n/k) of organic powdered materials using
pressed pellets in the mid-infrared spectral range is introduced that combines variable angle …

Twice-modulated light in Fourier Transform Infrared (FT-IR) spectrometers from reflective samples: avoiding distorted intensity values

TJ Johnson, TJ Baker, AM Bradley… - Applied …, 2022 - journals.sagepub.com
We document an artifact associated with the back reflection from samples or sampling
accessories in Fourier transform spectrometers. Samples oriented normal to the incoming …

Calculation of spectral optical constants using combined ellipsometric and reflectance methods for smooth and rough bulk samples

G Fortin - Applied Spectroscopy, 2021 - journals.sagepub.com
Spectra of the optical constants n and k of a substance are often deduced from
spectroscopic measurements, performed on a thick and homogeneous sample, and from a …

A method for generating quantitative vapor-phase infrared spectra of solids: results for phenol, camphor, menthol, syringol, dicyclopentadiene and naphthalene

MDW Schneider, TJ Baker, NK Scharko… - Journal of Quantitative …, 2024 - Elsevier
A method is presented to generate quantitative vapor-phase infrared spectra from
substances that naturally occur as solids with moderate volatility. The solid is gravimetrically …

Comparison of methods to derive infrared optical constants for organic materials for optical modeling

KA Peterson, BE Bernacki… - … , and Applications for …, 2023 - spiedigitallibrary.org
Reflectance spectroscopy, especially at infrared wavelengths, is often used for contact,
standoff, and remote sensing of solid materials. The reflectance spectra of solids, however …

Methods for Determining the Infrared Complex Refractive Indices n(λ) and k(λ) from Organic Solid Powders: Comparison of a Sucrose Single Crystal and a Pressed …

MO Yokosuk, DL Saunders, CT Resch… - ACS Applied Optical …, 2022 - ACS Publications
There exists a need to measure optical constants n and k for many materials, especially
organic solids in the infrared spectral region, but at present, there are only two established …

Modeling aerosol transmission spectra from n(λ) and k(λ) infrared optical constants measurements of organic liquids and solids

SP Lockwood, BE Bernacki, MJ Wilhelm, TL Myers… - Optics …, 2024 - opg.optica.org
The effects of light scattering and refraction play significantly different roles for aerosols than
for bulk materials, making it challenging to identify aerosolized chemicals using traditional …