Indole synthesis is among one of the most important tasks in N-heterocyclic chemistry.
Versatile synthetic methods have been developed for the establishment of an indole …

Nitrogen‐containing heterocycles have found remarkable applications in natural product
research, material sciences, and pharmaceuticals. Although the synthesis of this interesting …

Nitrogen heterocycles are some of the most important and sought‐after structural motifs in
synthetic chemistry. General methods that can be applied towards a structurally diverse …

Abstract The direct C H annulation of anilines or related compounds with internal alkynes
provides straightforward access to 2, 3‐disubstituted indole products. However, this …

Indoles are important structural motifs that are commonly found in a diverse array of natural
products, pharmaceuticals, and other functional molecules. Consequently, the development …

A mild, transition metal-free, diborane-mediated deoxygenation of nitro groups was
discovered that in situ generates nitrosoarene reactive intermediates. This new reactivity …

The reductive cyclization reaction of o-nitrostyrenes to generate indoles has been
investigated for three decades using CO as a cheap reducing agent, but it remains an …

N–Aryl bond formation under copper catalysis has played a pivotal role and has been
extensively used as a key step in the total syntheses of several therapeutic molecules. The …

An efficient three-component domino reaction of 2-bromoaldehydes, benzylamines, and
sodium azide has been developed for the synthesis of quinazoline derivatives. This domino …

A new method was developed for the synthesis of quinoxalines. This method employs N-
arylenamines and TMSN3 as the starting materials and implements two oxidative C–N bond …