Thermodynamic Modulation of Dihydrogen Activation Through Rational Ligand Design in GeII–Ni0 Complexes

PM Keil, S Ezendu, A Schulz, M Kubisz… - Journal of the …, 2024 - ACS Publications
A family of chelating aryl-functionalized germylene ligands has been developed and
employed in the synthesis of their corresponding 16-electron Ni0 complexes …

Metal-Ligand Cooperation at Phosphine-Based Acceptor Pincer Ligands

MR Tiddens, ME Moret - Metal-Ligand Co-operativity: Catalysis and the …, 2021 - Springer
Acceptor ligands, which predominantly withdraw electron density from a transition metal
center, often engage in weak metal-ligand interactions. These can be stabilized by flanking …

Development and application of a novel lead ion-selective electrode with the alkylamines modified molecular sieve as carrier

L Li, Z Yan, S Zhang - Journal of the Iranian Chemical Society, 2021 - Springer
The molecular sieve HZSM-5A was modified by incorporation of two alkylamines (C 8 H 17-
CH= NH, C 10 H 21-CH= NH; loading materials) and such two surfactant modified zeolites …

Reactions of Nickel (0)–Olefin Pincer Complexes with Terminal Alkynes: Cooperative C–H Bond Activation and Alkyne Coupling

MLG Sansores-Paredes, TTT Nguyen, M Lutz… - …, 2023 - ACS Publications
Metal–ligand cooperation can facilitate the activation of chemical bonds, opening reaction
pathways of interest for catalyst development. In this context, olefins occupying the central …

The chemistry and catalytic activity of dehydrogenative silylation and hydroboration of complexes bearing semirigid ligands with group 14 elements

NS Abeynayake - 2022 - scholarsjunction.msstate.edu
Incorporation of silicon in the ligand backbone would yield electron-rich metal complexes
upon coordination to transition metal complexes. The coordination chemistry of semirigid …

[PDF][PDF] Metal-ligand cooperativity at nickel π-pincer compounds

ME Moret - chemia.amu.edu.pl
Transition-metal complexes of π-ligands such as ketones and olefins occupy a prominent
place in homogeneous catalysis and organometallic chemistry. Binding a multiple bond to a …