[HTML][HTML] Surface organometallic and coordination chemistry toward single-site heterogeneous catalysts: strategies, methods, structures, and activities

C Coperet, A Comas-Vives, MP Conley… - Chemical …, 2016 - ACS Publications
The chemical industry relies on catalytic processes, which involve mainly heterogeneous
catalysts because they offer many advantages over their homogeneous counterparts such …

Bridging the Gap between Industrial and Well‐Defined Supported Catalysts

C Copéret, F Allouche, KW Chan… - Angewandte Chemie …, 2018 - Wiley Online Library
Many industrial catalysts contain isolated metal sites on the surface of oxide supports.
Although such catalysts have been used in a broad range of processes for more than 40 …

In situ grown two-dimensional TiO2/Ti3CN MXene heterojunction rich in Ti3+ species for highly efficient photoelectrocatalytic CO2 reduction

Y Xu, F Wang, S Lei, Y Wei, D Zhao, Y Gao… - Chemical Engineering …, 2023 - Elsevier
Converting CO 2 into chemicals is a promising avenue to mitigate the energy crisis and
global warming. Herein, two-dimensional (2D) heterojunctions of TiO 2/Ti 3 CN MXene were …

Computational modeling of heterogeneous Ziegler-Natta catalysts for olefins polymerization

N Bahri-Laleh, A Hanifpour, SA Mirmohammadi… - Progress in Polymer …, 2018 - Elsevier
Abstract Since 1963, when Karl Ziegler and Giulio Natta were jointly awarded the Nobel
Prize for their discoveries of the catalytic polymerization of olefins with Ti-chlorides and Al …

Electronic properties of Ti sites in Ziegler–Natta catalysts

A Piovano, M Signorile, L Braglia, P Torelli… - ACS …, 2021 - ACS Publications
Although Ziegler–Natta (ZN) catalysts play a major role in the polyolefin market, a true
understanding of their properties at the molecular level is still missing. In particular, there is a …

Synergistic Enhancement of the Photoelectrochemical Performance of TiO2 Nanorod Arrays through Embedded Plasmon and Surface Carbon Nitride Co …

N Chaulagain, KM Alam, S Kadian… - … Applied Materials & …, 2022 - ACS Publications
We report a unique photoanode architecture involving TiO2, g-C3N4, and AuNPs wherein a
synergistic enhancement of the photoelectrochemical (PEC) performance was obtained with …

Flexible ligands in heterogeneous catalysts for olefin polymerization: Insights from spectroscopy

A Piovano, E Groppo - Coordination Chemistry Reviews, 2022 - Elsevier
Heterogeneous catalysis for olefin polymerization is one of the most relevant industrial
processes in terms of worldwide diffusion, material volume, and economic turnover. At the …

A brief review on selected applications of hybrid materials based on functionalized cage-like silsesquioxanes

Ł John, J Ejfler - Polymers, 2023 - mdpi.com
Rapid developments in materials engineering are accompanied by the equally rapid
development of new technologies, which are now increasingly used in various branches of …

Vacancy and N dopants facilitated Ti3+ sites activity in 3D Ti3-xC2Ty MXene for electrochemical nitrogen fixation

Y Shi, Y Liu - Applied Catalysis B: Environmental, 2021 - Elsevier
Identification of the intrinsic active sites and understanding of the kinetics processes on
electrocatalysts is essential in the rational design of highly efficient electrochemical nitrogen …

New insights into defect‐mediated heterostructures for photoelectrochemical water splitting

X An, T Li, B Wen, J Tang, Z Hu, LM Liu… - Advanced Energy …, 2016 - Wiley Online Library
Understanding the interfacial electronic structures of heterojunctions, a challenging
undertaking, is extremely important to the design of photoelectrodes for efficient water …